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Nuclear spin high polarization method by dynamic nuclear polarization using soluble pentacene

机译:使用可溶性五烯偏振的动态核极化核自旋高偏振方法

摘要

PROBLEM TO BE SOLVED: To provide a method for improving the polarization rate of a nuclear spin.SOLUTION: A polarization rate of a nuclear spin can be effectively improved by a triplet DNP using a pentacene derivative represented by the following formula (A) as a polarization source. (where in the formula (A), R independently represents a C1-20 hydrocarbon group which may include at least one kind of atoms selected from a group consisting of a hydrogen atom (-H), a deuterium atom (-D) or an oxygen atom, a sulfur atom and a silicon atom, and at least one of Rs is a C1-20 hydrocarbon group which may include at least one kind of atoms selected from a group consisting of an oxygen atom, a sulfur atom and a silicon atom.)SELECTED DRAWING: None
机译:要解决的问题:提供一种提高核旋转的偏振率的方法。使用由下式(a)表示的五烯类DNP,可以通过三胞苷DNP得到有效改善核旋转的偏振速率作为a 极化源。 (其中在式(a)中,R独立地表示C1-20烃基,其可包括选自氢原子(-H),氘原子(-D)或AN的基团中的至少一种原子 氧原子,硫原子和硅原子,并且Rs中的至少一个是C1-20烃基,其可包括选自氧原子,硫原子和硅原子的至少一种原子 。)选定的绘图:无

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