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Copolymers and pigmented coatings containing the copolymers

机译:含有共聚物的共聚物和着色涂层

摘要

The present invention is obtained by copolymerization of a mixture of olefinically unsaturated monomers (a) in at least one organic solvent in the presence of at least one initiator, and has a glass transition temperature Tg of at least −30 ° C. A mixture of monomers (a) to be polymerized, wherein (a1) 10 mol% to 60 mol% of the following formula (I): embedded image wherein R 1 = C 1 -C 4 alkoxy At least one monomer of the formula H2C = CH2- (C = O) -O-Rx, H2C = CH, wherein R2 = C1-C4 alkyl and m = 0 to 2. (CH3)-(C = O) -O-Rx and H2C = CH2-O- (C = O) -Rx where Rx is an alkyl radical having from 1 to 20 carbon atoms. ) Comprising 40 mol% to 90 mol% of at least one olefinically unsaturated monomer selected from the group consisting of monomers, of monomers (a1) and (a2) relative to the total molar amount of monomers (a) used The copolymer (A) relates to a copolymer (A) in which the sum of the molar fractions is at least 90 mol% and the copolymerization is carried out at a temperature from 60 ° C. to 200 ° C. and a pressure of at least 2 bar.
机译:本发明是通过在至少一种引发剂存在下在至少一种有机溶剂中共聚烯属不饱和单体(A)的混合物而获得,并且具有至少-30℃的玻璃化转变温度Tg将单体(a)聚合,其中(a1)10mol%至60摩尔%的下式(i):嵌入图像,其中R 1 = C 1 -C 4烷氧基至少一种式H 2 C = CH2- (C = O)-O-Rx,H2C = CH,其中R2 = C1-C4烷基和M = 0至2.(CH 3) - (C = O)-O-Rx和H 2 C = CH2-O-(C = O)-Rx,其中Rx是具有1至20个碳原子的烷基。 )包含40mol%至90摩尔%的至少一种选自单体(A1)和(A2)的单体(A)的单体(a)的单体(a)组成的单体(a)的单体(a)的单体(a)的单体(a)的至少一种烯属不饱和单体涉及一种共聚物(a),其中摩尔级分的总和至少为90摩尔%,共聚在60℃至200℃的温度下进行和至少2巴的压力进行。

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