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Continuous prodn of basic zinc carbonate - by mixing a zinc salt soln with sodium carbonate soln contg. sodium hydroxide

机译:连续生产碱性碳酸锌-将锌盐溶液与碳酸钠溶液(续)混合。氢氧化钠

摘要

The continuous prodn. of basic zinc carbonate (I) is carried out by continuously contacting a Zn salt soln. with an NaOH-contg. Na2CO3 soln. while maintaining a pH of 7-10, the residence time of the mixt. in the reaction vessel being 10-1800 (pref. 45-300) sec. (I) is used as an activator and filler for rubber and for the prepn. of active Zn oxide (also used as a rubber activator and filler). The process gives high space-time yields of a high-purity product with good filterability; the filtrate has a very low Zn content, thus minimising waste-water treatment problems. The product can be converted (by calcination) into high-purity ZnO with a bulk density of 25-30 g/100 ml. The equiv. ratio of NaOH to Na2CO3 is pref. 25:75 to 80:20, esp. 50:50 to 60:40. The Zn salt is pref. Zn (NO3)2, ZnCl2 and/or ZnSo4, opt. in admixture with alkali(ne earth) metal salts. The initial solns. are pref. preheated to 50 degrees C before contact. The product is pref. converted into ZnO by calcination at =600 degrees C.
机译:连续产品通过使锌盐溶液连续接触来进行碱性碳酸锌(I)的制备。含NaOH的溶液Na2CO3溶液。同时保持pH值为7-10,即混合物的停留时间。在反应容器中的温度是10-1800秒(优选45-300秒)。 (I)用作橡胶和预浸料的活化剂和填料。活性氧化锌(也用作橡胶活化剂和填充剂)。该方法可提供高时空产率的高纯度产品,并具有良好的过滤性。滤液中的锌含量非常低,因此最大程度地减少了废水处理问题。该产品可以(通过煅烧)转化为堆积密度为25-30 g / 100 ml的高纯度ZnO。当量NaOH与Na2CO3的比例优选。 25:75至80:20,尤其是50:50至60:40。锌盐是优选的。 Zn(NO3)2,ZnCl2和/或ZnSo4,选择。与碱金属金属盐混合。最初的解决方案。是首选。接触前预热至> 50摄氏度。该产品是首选。在= 600摄氏度下通过煅烧转化为ZnO

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