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Recovery of hydrocarbon values by controlled eduction and oxidation of oil shale

机译:通过控制油页岩的析出和氧化来回收碳氢化合物

摘要

In the process for recovering energy values from oil shale by the cross-flow retort technique, an improvement is disclosed wherein controlled oxidation of non-vaporizable carbonaceous residue not only provides additional heat for the continuation of the oil educing process without application of external heat but also enables the continuation of a temperature profile which is below that at which adverse chemical and physical changes occur in the shale. According to the invention the moving bed is removed from exposure to external heat as soon as oil eduction has been completed in the upper bed regions. It is thereafter immediately exposed to unheated gases containing measured amounts of oxygen. Oxidation is initiated in those regions of the bed which are above about 800° F. The heat generated by such oxidation may be utilized, in place of externally heated gases, to transfer heat to the lower regions of the bed for oil eduction from those lower regions.
机译:在通过错流蒸馏技术从油页岩中回收能量值的方法中,公开了一种改进,其中不可蒸发的碳质残余物的受控氧化不仅为继续进行石油诱导过程提供了额外的热量,而且没有施加外部热量,而且还可以保持低于页岩中发生不利的化学和物理变化的温度曲线。根据本发明,一旦在上部床区域中完成油的排出,就将移动床从暴露于外部热量中移开。此后立即将其暴露于含有一定量氧气的未加热气体中。在床的高于约800°F的那些区域中开始氧化。可以利用由这种氧化产生的热量代替外部加热的气体,将热量传递到床的下部区域,以从较低的那些区域中排出油。地区。

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