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Method for producing flame retardant flexible polyurethane foams with blends of dibromoneopentyl glycol and flame retardant plasticizer
Method for producing flame retardant flexible polyurethane foams with blends of dibromoneopentyl glycol and flame retardant plasticizer
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机译:用二溴新戊二醇和阻燃增塑剂的混合物生产阻燃柔性聚氨酯泡沫的方法
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摘要
This invention is directed to a process for producing flame retardant flexible polyurethane foams having a porosity in the range between 0.5 and 10 cubic feet per minute. A polyol having an average molecular weight between about 250 and about 6,500 is reacted with toluene diisocyanate which comprises a mixture of the isomers of 2,4- and 2,6- toluene diisocyanate. The concentration of 2,4- toluene diisocyanate isomer is not critical. The formulation of the present invention includes a flame retardant mixture of a plasticizer and dibromoneopentyl glycol. The plasticizer is either a halogenated phosphonate or halogenated phosphate ester. Chlorine is the preferred halogen atom. The weight ratio of those ingredients is between about 50/50 and about 90/10 with the ratio 85/15 preferred. The concentration of that mixture is from about 1 to about 20 percent by weight of the polyol. Other ingredients that can be included in this formulation are water, a silicone surfactant, a tertiary amine catalyst, a tertiary amine co-catalyst, an auxiliary blowing agent and a tin catalyst. This process results in foam products that are flame retardant and suitable for automotive and furniture applications.
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