首页> 外国专利> 44 * toransuu4 *** toransuu4 *** arukirushikurohekishiru * shikurohekishiru * ansokukosann44shianofueniruesuteru

44 * toransuu4 *** toransuu4 *** arukirushikurohekishiru * shikurohekishiru * ansokukosann44shianofueniruesuteru

机译:44 * Toransu 4 *** Toransu 4 ***某某克路四郎(Kirushiro Hekishiru)*黑河纪四郎(Kuroheki Shiru)*安三子山44

摘要

NEW MATERIAL:A compound expressed by formula I (R is H or 1-10C alkyl). EXAMPLE:4-Cyanophenyl 4-[trans-4'-(trans-4''-propylcyclohexyl)cyclohexyl]benzoate. USE:A liquid crystal composition having about +8 dielectric anisotropy value and good stability to moisture, heat, light, etc., changing the threshold voltage and saturation voltage of the composition not so much. PROCESS:Bromobenzene is reacted with metallic magnesium, and the resultant product is then reacted with a compound expressd by formula II to afford a compound expressed by formula III. The resultant compound expressed by formula III is then dehydrated in the presence of a catalyst and then hydrogenated to give a compound expressed by formula IV, which is then halogenated with iodic acid, etc. and cynogenated with cuprous cyanide to afford a compond expressed by formula V. The resultant compound expressed by formula V is hydrolyzed in an aqueous solution of KOH to give a benzoic acid derivative expressed by formula VI, which is then converted into an acid chloride, and reacted with 4-cyanophenol to afford the aimed compound expressed by formula I .
机译:新材料:一种由式I表示的化合物(R为H或1-10C烷基)。实施例:4-氰基苯基4- [反式-4'-(反式-4′-丙基环己基)环己基]苯甲酸酯。用途:一种液晶组合物,具有约+8的介电常数各向异性值,并且对水分,热,光等具有良好的稳定性,因此不会太大地改变组合物的阈值电压和饱和电压。方法:使溴苯与金属镁反应,然后将所得产物与式II表示的化合物反应,得到式III表示的化合物。然后将得到的由式Ⅲ表示的化合物在催化剂的存在下脱水,然后氢化得到由式Ⅳ表示的化合物,然后将其用碘酸卤化,并用氰化亚铜氰化,得到由式Ⅳ表示的化合物。 V.将由式V表示的化合物在KOH水溶液中水解,得到由式VI表示的苯甲酸衍生物,然后将其转化为酰氯,并与4-氰基苯酚反应,得到由式V表示的目标化合物。公式一。

著录项

  • 公开/公告号JPH0231709B2

    专利类型

  • 公开/公告日1990-07-16

    原文格式PDF

  • 申请/专利权人 CHISSO CORP;

    申请/专利号JP19820085269

  • 发明设计人 SUGIMORI SHIGERU;KOJIMA TETSUHIKO;

    申请日1982-05-20

  • 分类号C09K19/30;C07C67/00;C07C253/00;C07C255/55;C09K19/42;G02F1/13;G09F9/00;G09F9/35;

  • 国家 JP

  • 入库时间 2022-08-22 06:22:48

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