CHIRAL DERIVATIVES OF 2-N-(NЪ-BENZYLPROLYL)-AMINO-BENZOPHENON AS REAGENT FOR OBTAINING OPTICALLY ACTIVE ALPHA-AMINOACIDS AND METHOD OF OBTAINING SAME

摘要

the invention u043eu0442u043du043eu0441u0438u0442u0441u00a0 to u0433u0435u0442u0435u0440u043eu0446u0438u043au043bu0438u0447u0435u0441u043au0438u043c u0441u043eu0435u0434u0438u043du0435u043du0438u00a0u043c, in particular to obtain u0445u0438u0440u0430u043bu044cu043du044bu0445 derivatives of 2 - n - (Nu044a - u0431u0435u043du0437u0438u043bu043fu0440u043eu043fu0438u043b) - u0430u043cu0438u043du043eu0431u0435u043du0437u043eu0444u0435u043du043eu043du0430 who u0438u0441u043fu043eu043bu044cu0437u0443u044eu0442u0441u00a0 as the reactants u0434u043bu00a0 u043fu043eu043bu0443u0447u0435u043du0438u00a0 optically active - amino acid in the aquatic environment. the objective is to obtain new compounds u0438u0437u043eu0431u0440u0435u0442u0435u043du0438u00a0 new way.a lead reaction of u0430u043cu0438u043du043eu043fu0440u043eu0438u0437u0432u043eu0434u043du043eu0433u043e 2 - n - (Nu044a - u0431u0435u043du0437u0438u043bu043fu0440u043eu043fu0438u043b) - u0430u043cu0438u043du043eu0431u0435u043du0437u043eu0444u0435u043du043eu043du0430 and u0430u043du0433u0438u0434u0440u0438u0434u043du044bu0445 or u0445u043bu043eu0440u0430u043du0433u0438u0434u0440u0438u0434u043du044bu0445 groups of polymer u043du043eu0441u0438u0442u0435u043bu00a0 ( preferably u0441u0443u043bu044cu0444u043eu0445u043bu043eu0440u0438u0440u043eu0432u0430u043du043du044bu0439 polystyrene, poorly made u0434u0438u0432u0438u043du0438u043bu0431u0435u043du0437u043eu043bu043eu043c, anhydride or u0445u043bu043eu0440u0430u043du0433u0438u0434u0440u0438u0434 u043fu043eu043bu0438u0430u043au0440u0438u043bu043eu0432u043eu0439 acid) in u043cu043eu043bu00a0u0440u043du043eu043c ratio 0.3 - 0.6. 1 in the presence of u0442u0440u0438u044du0442u0438u043bu0430u043cu0438u043du0430. 2 boeing. and 2 z. s - lu.the structure of u0441u043eu0435u0434u0438u043du0435u043du0438u00a0 @ where r1 = h, with r2 = - nh - r1;- nh - p2;r1 = - nh - p1;- nh - p2 and r2 = h, where p1 is the polymer of fort lu @ p2 is the polymer of fort lu @ in the n: m = 1: 0.66 - 2.33.