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method for the treatment of polyorganosilazanen and / or polyorganodisilylsilazanen with a genetic mineral salt and a chelating agent containing catalyst.
method for the treatment of polyorganosilazanen and / or polyorganodisilylsilazanen with a genetic mineral salt and a chelating agent containing catalyst.
A process for the treatment of polyorganosilazanes and/or polyorgano(disilyl)silazanes with an effective quantity of a catalyst system comprising (i) an ionic inorganic salt of the formula M30A-, and (II) a compound capable of complexing with the cation M+ of the salt. The M+cation is a metal ion or a quaternary ammonium ion, and A- is a compatible anion. The polysilazanes are selected from organopolysilazanes and organopoly(disilyl)silazanes. When treated in this manner, the polysilazanes are characterized by good thermal behavior and can, in particular, be used, after pyrolysis, as precursors of ceramic products.
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机译:用有效量的催化剂体系处理聚有机硅氮烷和/或聚(二甲硅烷基)硅氮烷的方法,该催化剂体系包括(i)式M30A-的离子无机盐,和(II)能够与阳离子M +络合的化合物盐。 M +阳离子是金属离子或季铵离子,而A-是相容性阴离子。聚硅氮烷选自有机聚硅氮烷和有机聚(二甲硅烷基)硅氮烷。当以这种方式处理时,聚硅氮烷的特征在于良好的热行为,并且尤其可以在热解之后用作陶瓷产品的前体。
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