首页> 外国专利> N'-T-BUTYL-N-HALOGENOMETHYLSULFENYL-N,N'-DIBENZOYL HYDRAZINE DERIVATIVE AND INSECTICIDAL COMPOSITION WITH THE SAME AS ACTIVE INGREDIENT

N'-T-BUTYL-N-HALOGENOMETHYLSULFENYL-N,N'-DIBENZOYL HYDRAZINE DERIVATIVE AND INSECTICIDAL COMPOSITION WITH THE SAME AS ACTIVE INGREDIENT

机译:N'-T-丁基-N-卤代甲基亚磺酰基-N,N'-二苯甲酰肼的衍生物和杀虫剂成分与活性成分相同

摘要

NEW MATERIAL:A compound of formula I (R1-R4 are each H, halogen, 1-4C, alkyl, 2-5C alkenyl, 1-4C alkynyl, 1-4C alkoxy, 1-4C haloalkyl, cyano, etc.; R5 is halomethyl). EXAMPLE:N'-tert. butyl-N-dichlorofluoromethylsulfenyl-N,N'-dibenzoyl hydrazine. USE:An insecticide. Useful for pest control in paddy, fields, orchards, forests or environmental and hygienic circumstances. Low toxic and highly active even to drug-resistant pests. PREPARATION:The objective compound of the formula I can be obtained by reaction in an inert solvent (e.g. hexane) in the presence of an appropriate base (e.g. triethylamine) at -20 deg.C to the boiling point of the solvent between (A) a N'-tert. butyl-N,N'-dibenzoyl hydrazine of formula II and (B) a halogenomethylsulfenyl halide of formula R5SX (X is halogen).
机译:新材料:式I的化合物(R1-R4分别为H,卤素,1-4C,烷基,2-5C烯基,1-4C炔基,1-4C烷氧基,1-4C卤代烷基,氰基等; R5是卤甲基)。示例:N'-tert。丁基-N-二氯氟甲基亚磺酰基-N,N'-二苯甲酰基肼。用途:杀虫剂。可用于稻田,田野,果园,森林或环境卫生环境中的害虫防治。低毒且对抗药性害虫具有高活性。制备:式Ⅰ的目标化合物可通过在惰性溶剂(例如己烷)中,在适当的碱(例如三乙胺)存在下,于-20℃至溶剂的沸点(A)之间反应来获得N'tert。式II的丁基-N,N'-二苯甲酰基肼和(B)式R5SX的卤代甲基亚磺酰卤(X为卤素)。

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