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Process for concentrating a polymer / emulsifying surfactant / hydrophobic liquid composition and concentrated polymer / emulsifying surfactant / hydrophobic liquid

机译:浓缩聚合物/乳化表面活性剂/疏水性液体组合物的方法和浓缩聚合物/乳化表面活性剂/疏水性液体

摘要

The use of falling-film evaporation and a concentration means such as centrifugal separation to dehydrate and concentrate a water-in-oil polymer emulsion or suspension is disclosed. In a preferred embodiment, a water-in-oil polymer composition containing less than about 25% active polymer solids is dehydrated in falling-film evaporator to produce an evaporator concentrate containing less than about 5.0% water. The evaporator concentrate then flows to a separation device such as a centrifuge, wherein oil is removed to produce a composition that is substantially a polymer and emulsifying surfactant-in-oil composition containing in excess of about 60 weight % polymer solids. The centrifuge raffinate may optionally be treated in a second separation means to capture additional polymer solids, with optional recycle of the oil-rich raffinate. The concentrated polymer composition is preferably stabilized with a steric stabilizer to produce a free flowing liquid product.
机译:公开了使用降膜蒸发和浓缩装置例如离心分离来脱水和浓缩油包水型聚合物乳液或悬浮液。在一个优选的实施方案中,将含有少于约25%的活性聚合物固体的油包水型聚合物组合物在降膜蒸发器中脱水以产生含有少于约5.0%的水的蒸发器浓缩物。蒸发浓缩物然后流到分离装置,例如离心机,在其中除去油以产生基本上为聚合物的组合物,并且乳化包含超过约60重量%的聚合物固体的油中表面活性剂组合物。离心提余液可以任选地在第二分离装置中进行处理,以捕集额外的聚合物固体,同时任选地再循环富油的提余液。浓缩的聚合物组合物优选用空间稳定剂稳定以产生自由流动的液体产物。

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