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Dye, process for its preparation, application of said dye, process for dyeing (including stamping) material containing hydroxy and / or carbonamide group, compound and its application

机译:染料,其制备方法,所述染料的应用,对含羟基和/或碳酰胺基团的材料进行染色(包括压印)的方法,化合物及其应用

摘要

Described are dyes which contain a fibre-reactive radical of the general formula IMAGE once or twice, also novel amino intermediates of the formula HN(R DEG )-(CH2)3-SO2-Y1. In these formulae, RA is hydrogen or lower alkyl which can be substituted by halogen, hydroxyl, cyano, lower alkoxy, lower alkoxycarbonyl, carboxyl, sulphamoyl, sulpho, sulphato or phosphato; R is alkyl having 1 to 6 carbon atoms which can be substituted by halogen, hydroxyl, cyano, lower alkoxy, lower alkoxycarbonyl, carboxyl, sulphamoyl, sulpho, sulphato, phosphato, phenyl or sulphophenyl, or is phenyl which can be substituted by halogen, lower alkyl, lower alkoxy, sulpho and/or carboxyl; X is halogen, cyanoamino, methylsulphonylamino, ethylsulphonylamino, carboxypyridinyl, aminocarbonylpyridinyl or a group of the formula -N(R)-W-(SO2-Y)Z with R, W, X and z having the above- or below-indicated significance; W is alkylene with 3 to 8 carbon atoms which can be substituted by alkoxy, halogen, alkoxycarbonyl, carboxyl, sulpho and/or sulphato or by an optionally sulpho-, carboxyl-, methoxy-, ethoxy-, and/or methyl-substituted phenyl radical or by such an optionally substituted phenyl radical and a sulpho, sulphato or carboxyl group or by a heterocyclic radical; Y is vinyl, beta -sulphatoethyl, beta -thiosulphatoethyl, beta -phosphatoethyl, beta -alkanoyloxyethyl, beta -sulphobenzoyloxyethyl, ( beta -(p-toluenesulphonyloxy)ethyl or beta -haloethyl; z is 1 or 2; R DEG is phenyl which can be substituted by 1, 2 or 3 substituents from the group consisting of halogen, lower alkyl, lower alkoxy, sulpho and carboxyl; and Y1 has one of the significances of Y or is beta -hydroxyethyl. The dyes are used for preparing strong and fast dyeings on hydroxyl- and/or carboxamido-containing materials, in particular fibre materials, for example cellulose fibre materials, wool and synthetic polyamide.
机译:描述了包含一或两次通式的纤维反应性基团的染料,以及通式HN(R DEG)-(CH 2)3 -SO 2 -Y 1的新型氨基中间体。在这些式中,R A是氢或可被卤素,羟基,氰基,低级烷氧基,低级烷氧基羰基,羧基,氨磺酰基,磺基,硫酸根或磷酸根取代的低级烷基; R为具有1-6个碳原子的烷基,可被卤素,羟基,氰基,低级烷氧基,低级烷氧羰基,羧基,氨磺酰基,磺基,硫酸根,磷酸根,苯基或磺基苯基取代,或为可被卤素取代的苯基,低级烷基,低级烷氧基,磺基和/或羧基; X是卤素,氰基氨基,甲基磺酰基氨基,乙基磺酰基氨基,羧基吡啶基,氨基羰基吡啶基或具有-R(W)-X和z具有以上或以下所示含义的式-N(R)-W-(SO 2 -Y)Z的基团; W是具有3至8个碳原子的亚烷基,其可以被烷氧基,卤素,烷氧基羰基,羧基,磺基和/或硫酸根或任选被磺基,羧基,甲氧基,乙氧基和/或甲基取代的苯基取代自由基或通过这样的任选取代的苯基和磺基,硫酸根或羧基或杂环基; Y是乙烯基,β-磺基乙基乙基,β-硫代磺基乙基乙基,β-磷酸乙基基团,β-链烷酰氧基乙基,β-磺基苯甲酰氧基乙基,(β-(对甲苯磺酰氧基)乙基或β-卤代乙基; z为1或2; R DEG为苯基,其可以Y 1被卤素,低级烷基,低级烷氧基,磺基和羧基组成的组中的1、2或3个取代基取代;并且Y 1具有Y的意义之一或为β-羟乙基。在含羟基和/或羧酰胺基的材料,特别是纤维材料,例如纤维素纤维材料,羊毛和合成聚酰胺上,进行强而快速的染色。

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