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BLOCK CO-POLYMER STARRED WITH AN AROMATIC VINYL MONOMER AND A CONJUGUATED DIENE, PRODUCTION PROCESS OF THE SAID CO-POLYMER AND COMPOSITIONS INCLUDING IT AND CRYSTAL POLYSTYRENE
BLOCK CO-POLYMER STARRED WITH AN AROMATIC VINYL MONOMER AND A CONJUGUATED DIENE, PRODUCTION PROCESS OF THE SAID CO-POLYMER AND COMPOSITIONS INCLUDING IT AND CRYSTAL POLYSTYRENE
the invention relates to a copolymer block of general formula u00a2s1 star s2 - s3 b1 / b2). m - x - u00a2b2 (b1 / s3 - s2. n in which x is a radical derived from a poly functional coupling agent.m and n are integers greater than zero as m + n is equal to 3 or 4, s1 and s2, each representing a block of a polymer of at least one vinylaromatique monomer.b is a polymer block of a conjugated diene and at least one (b1 / s3) is a block copolymer of a monomer of at least one vinylaromatique statistics and at least one conjugated diene40 to 75% by weight of (b1 / s3) consisting of monomer units derived from vinylaromatique.characterized in that the block b2 contains more than 40% by weight and less than 90% by weight of the total copolymer block of conjugated diene content in the dark.the invention also relates to the process for the production of the copolymer and the composition comprising the copolymer and polystyrene.such compositions exhibit excellent mechanical properties and transparency.
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机译:本发明涉及一种通式为“ S 2 -S 3 B 1 / B 2”的共聚物嵌段。 m-x- u00a2b2(b1 / s3-s2。n其中,x是衍生自多官能偶联剂的基团。m和n是大于零的整数,因为m + n等于3或4,s1和s 2,每个代表至少一种乙烯基芳族单体的聚合物的嵌段。b是共轭二烯的聚合物嵌段,并且至少一个(b 1 / s 3)是具有至少一种乙烯基芳族单体统计和至少一种由乙烯基芳烃衍生的单体单元组成的(b1 / s3)的共轭二烯40-75%(重量),其特征在于嵌段b2占共聚物嵌段总数的40%(重量)以上和90%(重量)以下在黑暗中共轭二烯的含量。本发明还涉及共聚物的生产方法以及包含该共聚物和聚苯乙烯的组合物。这种组合物表现出优异的机械性能和透明度。
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