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Cerium (IV) catalyst compounds and promoting combustion of hydrocarbon fuels therewith

机译:铈(IV)催化剂化合物并由此促进烃类燃料的燃烧

摘要

Novel cerium (IV) oxidic compounds, well suited as catalysts, e.g., for the clean combustion of hydrocarbon fuels and for the "drying" of paint compositions, each Ce(IV) atom of which being coordinated with two anions of an organic oxyacid advantageously having a pKa greater than 1, preferably greater than 2, or a mixture of such oxyacids, and the oxidic oxygen atom or atoms of which being other than those comprising the organic oxyacids; representative such novel cerium (IV) oxidic compounds, whether yellow crystalline solids or yellow liquids, have the formula: PP(H.sub.2 O).sub.p [CeO(A).sub.2 ·(AH). sub.n . multidot.].sub.mPPin which the radicals A, which may be the same or different, are each the residue of an organic oxyacid of formula AH, p is an integer ranging from 0 to 5, n ranges from 0 to 2 and m is an integer ranging from 1 to 12.
机译:新型铈(IV)氧化物,非常适合用作催化剂,例如,用于烃类燃料的清洁燃烧和涂料组合物的“干燥”,其每个Ce(IV)原子均与有机含氧酸的两个阴离子配位具有大于1的pKa,优选大于2,或这些含氧酸的混合物,并且其一个或多个氧化性氧原子不同于包含有机含氧酸的那些;具有代表性的此类新型铈(IV)氧化化合物,无论是黄色结晶固体还是黄色液体,其化学式为:

(H.sub.2 O).sub.p [CeO(A).sub.2· (啊)。子m P,其中基团A可以相同或不同,每个基团为式AH的有机含氧酸的残基,p为0至5的整数,n范围是0到2,m是1到12的整数。

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