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Bismaleimide compound having perfluorononenyloxy group, production process thereof and bismaleimide resin material

机译:具有全氟壬烯氧基的双马来酰亚胺化合物,其制备方法和双马来酰亚胺树脂材料

摘要

NEW MATERIAL:To bismaleimide compound, expressed by formula I (C9F17 contains one double bond and may be suitably branched; H in the aromatic ring can be substituted with alkyl, alkoxy, F, Cl or Br; two maleimide groups are respectively bound to the aromatic rings at the o-, m- or p-positions with respect to the ester bonds) and having perfluorononenyloxy group. EXAMPLE:Bis(4-maleimidophenyl)-5-(perfluorononenyloxy)isophthalate. USE:A raw material for bismaleimide resins excellent both in heat resistance and in moisture unabsorbence. PREPARATION:An acid chloride compound, expressed by formula II and having the perfluorononenyloxy group is reacted with a hydroxyphenylmaleimide compound expressed by formula III to afford the compound expressed by formula I.
机译:新材料:对于双马来酰亚胺化合物,用式I表示(C9F17含有一个双键并且可以适当地分支;在芳香环中的H可以被烷基,烷氧基,F,Cl或Br取代;两个马来酰亚胺基团分别与相对于酯键在邻,间或对位的芳环)并具有全氟壬烯氧基。实例:双(4-马来酰亚胺基苯基)-5-(全氟壬烯氧基)间苯二甲酸酯。用途:双马来酰亚胺树脂的原料,其耐热性和吸湿性均优异。制备:使式II表示的具有全氟壬烯氧基的酰氯化合物与式III表示的羟基苯基马来酰亚胺化合物反应,得到式I表示的化合物。

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