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CALIXPYRROLES, CALIXPYRIDINOPYRROLES AND CALIXPYRIDINES

机译:加利福尼亚吡咯烷酮,加利福尼亚吡咯烷酮吡咯烷酮和加利福尼亚吡咯烷酮

摘要

The present invention provides calixpyrrole, calixpyridinopyrrole, andcalixpyridine macrocycles, having 4, 5, 6, 7 or 8 heterocyclic rings, as wellassyntheses, derivatives, conjugates, multimers, and solid supports thereof.Suchmacrocycles have proved to be effective and selective ion- and neutralmolecule-binding agents forming supramolecular ensembles, and ion- and neutralmolecule-separation agents. The macrocycles are fully meso-non-hydrogen-substituted porphyrinogens, a few molecules of which were previously known butnot recognized as possessing anion- or molecule-binding properties. Thebinding mode is noncovalent, primarily that of hydrogen-bonding, therebyproviding a new mode for liquid chromatography, that of Hydrogen BondingLiquid Chromatography. Further useful applications of the macrocyles providedherein include environmental remediation by removal of undesired ions orneutralmolecules, and removal of phosphate for kidney dialysis.
机译:本发明提供杯盖吡咯,杯盖吡啶并吡咯和杯吡啶并具有4、5、6、7或8个杂环的大环如合成,衍生物,缀合物,多聚体和固体支持物。这样大环化合物已被证明是有效的,并且对离子和中性离子具有选择性分子-形成超分子整体的结合剂,以及离子和中性的分子分离剂。大环完全是中观非氢的取代的卟啉原,以前已知其中一些分子,但不被认为具有阴离子或分子结合特性。的结合模式是非共价的,主要是氢键结合,因此为液相色谱提供了一种新的模式,即氢键键合液相色谱。所提供的大环的进一步有用的应用本文包括通过去除不需要的离子进行的环境修复或中性分子,并去除磷酸盐以进行肾脏透析。

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