electrochemical measuring cell for the detection and for the determination of gases and vapours, in particular of halogenated hydrocarbons

摘要

An electrochemical measuring cell has a three-electrode system including electrode, counter electrode and reference electrode in an electrolyte. The measuring cell has an additive promoting the electrochemical reaction and is selective and highly sensitive for the detection of hydrogen halides and also provides a stable measuring signal. A measuring cell of this kind has an additive of tetrachloroauric acid in the electrolyte for detecting hydrochloric acid with all electrodes being made of gold. The counter electrode is protected by a cation exchange membrane to provide a further improvement.