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METHOD AND DEVICE FOR MEASURING NITRIC ACID CONCENTRATION BY CONTINUOUS FLOW ANALYSIS METHOD

机译:连续流动分析法测定硝酸浓度的方法和装置

摘要

PROBLEM TO BE SOLVED: To rapidly and accurately measure the concentration of not only a high-concentration nitric acid solution but also a low-concentration nitric acid solution by using measurement light including a plurality of wavelengths with an absorption region for a nitric acid ion and selecting the wavelength of measurement light according to the nitric acid concentration of a sample liquid and measuring absorbance. ;SOLUTION: A target sample liquid is selected by a switching valve 12 and the sample loop of an injection valve 11 is filled with the sample liquid by a suction pump 14. Then, the injection valve 11 is opened, the sample liquid is fed to a pipeline 40 and is fed to a measurement part 30 via a dilution part 20 by a carrier liquid that flows in the pipeline 40, and the absorbance is measured. When the nitric acid concentration level of the sample liquid is known in advance, the wavelength of the measurement light is selected according to the nitric acid concentration level and an absorbance is measured by the measurement light with a proper wavelength. Concretely speaking, light with a wavelength of 280nm-330mm has an absorption liquid for nitric acid ion so that it is used for measurement. The wavelength of the measurement light is selected after measuring the nitric acid concentration level of the sample liquid in advance by preliminary measurement when the level of the nitric acid concentration is known.;COPYRIGHT: (C)1998,JPO
机译:解决的问题:通过使用具有多个波长的测定光以及硝酸离子的吸收区域,来快速且准确地不仅测量高浓度硝酸溶液的浓度,而且还快速测量低浓度硝酸溶液的浓度。根据样品液中的硝酸浓度选择测量光的波长并测量吸光度。 ;解决方案:通过切换阀12选择目标样品液,并通过抽水泵14将样品液注入进样阀11的样品环。然后,打开进样阀11,将样品液进料至在管道40中流过的载液经由稀释部20而被供给至测定部30,并测定吸光度。当预先知道样品液体的硝酸浓度水平时,根据硝酸浓度水平选择测量光的波长,并通过具有适当波长的测量光来测量吸光度。具体地说,波长为280nm-330mm的光具有用于硝酸离子的吸收液,因此可以用于测量。在已知硝酸浓度水平的情况下,通过预先测量预先测量样品液体的硝酸浓度水平后,选择测量光的波长。COPYRIGHT:(C)1998,JPO

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