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MOLTEN CARBONATE TYPE FUEL CELL POWER GENERATION-EXHAUST GAS RECOVERY COMBINED SYSTEM USING BY-PRODUCT GAS IN PRODUCTION OF IRON

机译:钢铁生产中副产煤气用碳酸氢盐型燃料电池发电-排气综合利用系统

摘要

PROBLEM TO BE SOLVED: To provide a gas with-global-warming-effect fixing type energy saving system for utilizing carbon dioxide transport ability of a molten carbonate type fuel cell, to recover and fix carbon dioxide concentrated in an anode exhaust gas, while supplying two kinds of by-produced gases in iron production as gases for anode and cathode electrodes of the molten carbonate type fuel cell so as to attain highly efficient power generation. SOLUTION: A coke oven gas COG or its steam-reformed gas out of by-produced gases in iron production is used for gas supplied to an anode, combustion exhaust gas of a blast furnace gas BFG after regulated to a prescribed carbon dioxide/oxygen concentration ratio is used for gas supplied to a cathode, and they are supplied separately to a molten carbonate fuel cell MCFC to attain highly efficient power generation, so that iron production by-product gas effectively utilized type energy saving power generation is realized. Carbon dioxide concentrated in the anode is isolated and recovered with low energy by utilizing carbon dioxide transport ability of the molten carbonate type fuel cell MCFC to be utilized for a raw material for existing chemicals so as to be fixed as chemical substances, thereby cross-industrial type process efficiency ranging over iron production-chemistry is improved, and discharge of gases having global warming effect can be reduced at the same time.
机译:要解决的问题:提供一种具有全球变暖效应的固定型节能系统,该系统利用熔融碳酸盐型燃料电池的二氧化碳传输能力,在供给的同时回收和固定阳极废气中浓缩的二氧化碳。钢铁生产中使用的两种副产气体作为熔融碳酸盐型燃料电池的阳极和阴极气体,以实现高效发电。解决方案:炼铁过程中产生的副产气体中的焦炉煤气COG或其蒸汽重整气体用于提供给阳极的气体,高炉煤气BFG的燃烧废气调节至规定的二氧化碳/氧气浓度后该比率用于提供给阴极的气体,并且将它们分别提供给熔融碳酸盐燃料电池MCFC以实现高效发电,从而实现了铁生产副产物气体的有效利用型节能发电。通过利用熔融碳酸盐型燃料电池MCFC的二氧化碳传输能力来分离并回收低浓度集中在阳极中的二氧化碳,该熔融碳酸盐型燃料电池MCFC被用作现有化学品的原料,从而被固定为化学物质,从而实现跨行业的工业化。改善了铁生产-化学过程中的各种类型的工艺效率,并且可以同时减少具有整体变暖作用的气体的排放。

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