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Production manner null of the olefins which use the alumina catalytic converter and this catalytic converter for dehydration reaction
Production manner null of the olefins which use the alumina catalytic converter and this catalytic converter for dehydration reaction
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机译:使用氧化铝催化转化器和该催化转化器进行脱水反应的烯烃的生产方式无效
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摘要
PURPOSE:To obtain an olefin useful as for various organic synthetic raw materials and polymer raw materials from a lower alcohol by a simple device in high yield and in high selectivity for a long period of time by using a specific catalyst. CONSTITUTION:In producing an olefin by dehydrating 2-4c alcohol, the objective compound is industrially and advantageously obtained preferably under a pressure condition so a to liquefy the compound at a normal temperature at 150-500 deg.C, preferably 250-400 deg.C by using a catalyst prepared by blending gamma-alumina catalyst with 0.5-5wt.%, preferably 0.5-3wt.% SiO2 and suppressing the transition of crystal phase from gamma-alumina to alpha-alumina and not making the reaction product into a heavy substance without deteriorating the catalyst for many hours.
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