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PYRAZOLE DERIVATIVES

机译:吡唑衍生物

摘要

Pyrazole derivatives of formula wherein R1 represents C1-C4 alkyl group, C2-C4 alkenyl group or C2-C4 halogenalkenyl group; R2 represents a hydrogen atom, C1-C4 alkyl group, C1-C4 halogenalkyl group or C2-C4 alkoxyalkyl group; X represents C1-C4 alkyl group, C1-C4 halogenalkyl group, C2-C4 alkoxyalkyl group, a halogen atom, C1-C4 alkoxy group or C1-C4 halogenalkyl group; p is an integer of 0, 1 or 2; R3 represents C1-C4 alkyl group, C1-C4 halogenalkyl group, C3-C6 cycloalkyl group, C3-C6 alkenylalkyl group, C3-C6 alkynylalkyl group, C3-C6 halogenalkenylalkyl group or C2-C4 alkoxyalkyl group; each of R4, R5, R6, and R7 independently represents a hydrogen atom, C1-C4 alkyl group, C1-C4 halogenalkyl group or C2-C4 alkoxyalkyl group; n is an integer of 0, 1, or 2 and Q represents a hydrogen atom or group -A-B, wherein A represents where each of R8 and R9 independently represents a hydrogen atom or C1-C4 alkyl group, and B represents C1-C12 alkyl group, C3-C10 cycloalkyl group or group wherein Y represents C1-C4 alkyl group, C1-C4 alkoxy group, C1-C4 halogenalkyl group, nitro group or a halogen atom and m is an integer of 0, 1 or 2; in case except for compounds of formula (I), where p is 1, R3 represents C1-C4 alkyl group, X represents C1-C4 alkyl group, and all of R4, R5, R6, and R7 represent hydrogen atoms, and compounds of formula (I), where p is 2, R3 represents C1-C4 alkyl group, two X represent C1-C4 alkyl groups, and all of R4, R5, R6, and R7 represent hydrogen atoms. 2. Pyrazole derivatives according to Claim 1, where R1 represents C1-C4 alkyl group. 3. Pyrazole derivatives according to Claim 2, where R1 methyl or ethyl. 4. Pyrazole derivatives according to Claim 1, where R2 represents C1-C4 alkyl group. 5. Pyrazole derivatives according to Claim 1, where R3 represents C1-C4 alkyl group, C1-C4 halogenalkyl group, C3-C6 alkenylalkyl group or C3-C6 alkynylalkyl group. 6. Pyrazole derivatives according to Claim 5, where R3 represents methyl, -CH2CH2F. allyl or propargyl 7. Pyrazole derivatives according to Claim 1, where each of R4, R5, R6, and R7 independently represents a hydrogen atom or C1-C4 alkyl group. 8. Pyrazole derivatives according to Claim 1, where p is 1 and X represents C1-C4 alkyl group, C1-C4 halogenalkyl group, a halogen atom or C1-C4 alkoxy group, present as substitute at the ring 5-position of thiochromane. 9. Pyrazole derivatives according to Claim 8, where X represents methyl, trimethylfluoride, a chlorine atom or methoxy. 10. Pyrazole derivatives according to Claim 1, where p is 2 and one of X represents C1-C4 alkyl group, a halogen atom or C1-C4 halogenalkyl group, present as substitute at the ring 5-position of thiochromane, and another X represents a halogen atom, C1-C4 alkoxy group or C1-C4 alkyl group, present as substitute at the ring 8-position of thiochromane. 11. Pyrazole derivatives according to Claim 10, where one of X represents methyl, trimethylfluoride, a chlorine atom or methoxy present as substitute at the ring 5-position of thiochromane, and another X represents a chlorine atom, a fluorine atom, methoxy or methyl, present as substitute at the ring 8-position of thiochromane. 12 Pyrazole derivatives according to Claim 1, where n is 0 or 2. 13. Pyrazole derivatives according to Claim 1, where Q represents a hydrogen atom14. 14. Pyrazole derivatives according to Claim 1, where Q represents group -A-B, where A represents 15. Pyrazole derivatives according to Claim 1, where Q represents group -A-B, where B is selected from the group, including C1-C4 alkyl group, C3-C7 cycloalkyl group or group wherein Y1 represents C1-C4 alkyl group or a halogen atom and m1 is an integer of 0, 1 or 2. 16. Pyrazole derivatives according to Claim 15, where Q represents group -A-B, where B is selected from the group including propyl, cyclohexyl and toluyl. 17. Pyrazole derivatives according to Claim 1, where Q represents group -A-B, where combination A and B represents group, selected from a class, including 18. Pyrazole derivatives according to Claim 1, where Q represents group -A-B, where combination A and B represents group, selected from a class, including and 19. Carboxylic acid of formula (III) wherein X represents C1-C4 alkyl group, C1-C4 halogenalkyl group, C2-C4 alkoxyalkyl group, a halogen atom, C1-C4 alkoxy group or C1-C4 halogenalkoxy group; p is an integer of 0, 1 or 2; R3 represents C1-C4 alkyl group, C1-C4 halogenalkyl group, C3-C6 cycloalkyl group, C3-C6 alkenylalkyl group, C3-C6 alkynylalkyl group, C3-C6 halogenalkenylalkyl group or C2-C4 alkoxyalkyl group; each of R4, R5, R6, and R7 independently represents a hydrogen atom, C1-C4 alkyl group, C1-C4 halogenalkyl group or C2-C4 alkoxyalkyl group; n is an integer of 0, 1, or 2 and in case except for compounds of formula (III), where p is 1, R3 represents C1-C4 alkyl group, X represents C1-C4 alkyl group, and all of R4, R5, R6, and R7 represent hydrogen atoms, and compounds of formula (III), where p is 2, R3 represents C1-C4 alkyl group, two X represent C1-C4 alkyl groups, and all of R4, R5, R6, and R7 represent hydrogen atoms. 20. Herbicide, containing as an active compound pyrazole derivative of general formula by any of the preceding Claims from 1 to 18.
机译:下式的吡唑衍生物:其中R 1代表C 1 -C 4烷基,C 2 -C 4烯基或C 2 -C 4卤代烯基; R 2表示氢原子,碳原子数为1〜4的烷基,碳原子数为1〜4的卤代烷基或碳原子数为2〜4的烷氧基烷基。 X代表C1-C4烷基,C1-C4卤代烷基,C2-C4烷氧基烷基,卤原子,C1-C4烷氧基或C1-C4卤代烷基; p是0、1或2的整数; R 3表示C1-C4烷基,C1-C4卤代烷基,C3-C6环烷基,C3-C6烯基烷基,C3-C6炔基烷基,C3-C6卤代烯基烷基或C2-C4烷氧基烷基; R 4,R 5,R 6和R 7分别独立地表示氢原子,碳原子数为1〜4的烷基,碳原子数为1〜4的卤代烷基或碳原子数为2〜4的烷氧基烷基。 n是0、1,或2的整数,并且Q表示氢原子或-AB基,其中A表示其中R 8和R 9各自独立地表示氢原子或C 1 -C 4烷基,并且B表示C 1 -C 12烷基,C 3 -C 10环烷基或其中Y表示C 1 -C 4烷基,C 1 -C 4烷氧基,C 1 -C 4卤代烷基,硝基或卤原子且m为0的整数的基团, 1或2;在式(I)的化合物除外的情况下,其中p为1,R 3代表C 1 -C 4烷基,X代表C 1 -C 4烷基,且R 4,R 5,R 5全部为在图6中,R 7代表氢原子,以及式(I)的化合物,其中p是2,R 3代表C1-C4烷基,两个X代表C1-C4烷基,并且所有R 4,R 5,R 6和R 7表示氢原子。 2.根据权利要求1的吡唑衍生物,其中R 1代表C 1 -C 4烷基。 3.根据权利要求2的吡唑衍生物,其中R 1为甲基或乙基。 4.根据权利要求1的吡唑衍生物,其中R 2代表C 1 -C 4烷基。 5.根据权利要求1的吡唑衍生物,其中R 3代表C 1 -C 4烷基,C 1 -C 4卤代烷基,C 3 -C 6烯基烷基或C 3 -C 6炔基烷基。 6.根据权利要求5的吡唑衍生物,其中R 3代表甲基,-CH 2 CH 2F。 7.根据权利要求1的吡唑衍生物,其中R 4,R 5,R 6和R 7各自独立地表示氢原子或C 1 -C 4烷基。 8,根据权利要求1的吡唑衍生物,其中p为1,X代表C 1 -C 4烷基,C 1 -C 4卤代烷基,卤原子或C 1 -C 4烷氧基,作为取代基存在于硫代铬烷的环5位。 9.根据权利要求8的吡唑衍生物,其中X代表甲基,三甲基氟化物,氯原子或甲氧基。 10,根据权利要求1的吡唑衍生物,其中p是2,X中的一个代表在硫代苯并环的5-环上取代的C1-C4烷基,卤原子或C1-C4卤代烷基,另一个X代表作为取代基存在于硫代色烷的环8位的卤原子,C 1 -C 4烷氧基或C 1 -C 4烷基。 11.根据权利要求10的吡唑衍生物,其中X之一代表甲基,三甲基氟化物,作为取代基存在于硫代铬烷的环5-位的氯原子或甲氧基,另一个X代表氯原子,氟原子,甲氧基或甲基。作为取代基存在于硫代苯并环的8位。 12.根据权利要求1的吡唑衍生物,其中n是0或2。13.根据权利要求1的吡唑衍生物,其中Q表示氢原子。 14.根据权利要求1的吡唑衍生物,其中Q代表-AB基,其中A代表15.根据权利要求1的吡唑衍生物,其中Q代表-AB基,其中B选自包括C 1 -C 4烷基的基团, 16.根据权利要求15所述的吡唑衍生物,其中,Q 1为C 3 -C 7环烷基或基团,其中Y 1代表C 1 -C 4烷基或卤素原子,m 1为0、1或2的整数。 -AB,其中B选自丙基,环己基和甲苯基。 17.根据权利要求1的吡唑衍生物,其中Q表示基团-AB,其中组合A和B表示基团,选自包括以下的类别。18.根据权利要求1的吡唑衍生物,其中Q表示基团-AB,其中组合A和B B代表选自以下的基团,包括19和19。式(III)的羧酸,其中X代表C 1 -C 4烷基,C 1 -C 4卤代烷基,C 2 -C 4烷氧基烷基,卤素原子,C 1 -C 4烷氧基。或C 1 -C 4卤代烷氧基;或p是0、1或2的整数; R 3表示C1-C4烷基,C1-C4卤代烷基,C3-C6环烷基,C3-C6烯基烷基,C3-C6炔基烷基,C3-C6卤代烯基烷基或C2-C4烷氧基烷基; R 4,R 5,R 6和R 7分别独立地表示氢原子,碳原子数为1〜4的烷基,碳原子数为1〜4的卤代烷基或碳原子数为2〜4的烷氧基烷基。 n是0、1,或2的整数,并且在式(III)的化合物除外的情况下,其中p是1,R 3代表C1-C4烷基,X代表C1-C4烷基,并且所有R 4,R 5,R 6,并且R 7代表氢原子,以及式(III)的化合物,其中p是2,R 3代表C 1 -C 4烷基,两个X代表C 1 -C 4烷基,并且所有R 4 ,R 5,R 6和R 7表示氢原子。 20.除草剂,其包含作为活性化合物的前述权利要求1至18中任一项的通式的吡唑衍生物。

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