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METHOD FOR PRODUCTION OF OLIGOMETHYLENEUREA USABLE AS A FERTILISER

机译:用作肥料的寡聚甲基尿嘧啶的生产方法

摘要

An oligomethylene urea product usable as a fertilizer can be more efficiently prepared in several steps by:a) introducing at least urea and an aqueous solution of formaldehyde in the overall molar ratio of urea to formaldehyde of the step 1:1-2:1 into a reactor with a retention time of at least 0.5 h, a temperature maintained in the range of 40 to 95° C. and a pH maintained in the range of 6.5 to 11, in order to produce a methylol urea composition,b) conducting the methylol urea composition to a second reactor with a temperature maintained in the range of 5 to 35° C. and a pH maintained in the range of 1.8 to 3.5, in order to produce a first oligomethylene urea slurry, and optionally,c) conducting the methylol urea composition or the first oligomethylene urea slurry to a third reactor with a temperature maintained in the range of 5 to 35° C. and a pH maintained in the range of 1.8 to 3.5, to produce a second oligomethylene urea slurry,d) conducting the oligomethylene urea slurry, selected from the first and the second oligomethylene urea slurry, to a filter and filtering it to form an oligomethylene urea precipitate and a filtrate,e) recycling the filtrate to the reactor, selected from the second and the third reactor, andf) neutralizing and drying the oligomethylene precipitate and recovering it as said oligomethylene urea product.
机译:可以通过以下步骤更有效地制备可用作肥料的低聚亚甲基脲产品:a)将至少尿素和甲醛水溶液以步骤1:1-2:1的尿素与甲醛的总摩尔比引入为了产生羟甲基脲组合物,保持时间为至少0.5h,温度保持在40至95℃,pH保持在6.5至11的反应器,b)进行为了生产第一低聚亚甲基脲浆液,将羟甲基脲组合物送入第二反应器,该第二反应器的温度保持在5-35℃,pH保持在1.8-3.5,并任选地,c)进行将羟甲基脲组合物或第一低聚亚甲基脲浆液送入第三反应器,其温度保持在5-35℃,pH维持在1.8-3.5,以生产第二低聚亚甲基脲浆液,d)低聚亚甲基脲浆液,选择将第一低聚亚甲基脲浆液和第二低聚亚乙基脲浆液过滤到过滤器中,以形成低聚亚甲基脲沉淀物和滤液,e)将滤液再循环至选自第二和第三反应器的反应器中,以及f)中和并干燥该低聚亚甲基沉淀物被回收并作为所述的低聚亚甲基脲产物。

著录项

  • 公开/公告号HU9802939A3

    专利类型

  • 公开/公告日1999-04-28

    原文格式PDF

  • 申请/专利权人 KEMIRA AGRO OY HELSINKI;

    申请/专利号HU19980002939

  • 发明设计人

    申请日1996-07-26

  • 分类号C05C9/02;

  • 国家 HU

  • 入库时间 2022-08-22 02:27:16

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