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A catalyst for the alkylation of a c4 - c5 isoparaffin at least one c2 - c6 olefin

机译:用于使c4-c5异链烷烃至少一种c2-c6烯烃烷基化的催化剂

摘要

The present invention relates to a catalyst comprising an organic or mineral porous support, preferably silica, and a phase acid containing the compound b (oso2 cf3) 3 and at least one acid chosen from the group formed by the sulfuric acid (h2) and so4 trifluoromethanesulfonic acid (cf3 so3 h), said support has been impregnated with the acid phase, the catalyst being such that it is essentially constituted of particles of average diameter ranging from 0,1 and 150 μm, the said catalyst is characterized in that the acid phase comprises: & br / - from 0,1 and 70% by weight of compound b (oso2 cf3) 3; & br / - between 0 and 90% by weight of h2 so4; & br / - between 0 and 90% by weight of cf3 so3 h. & br / the invention also concerns the preparation and the use of the catalyst in a catalytic alkylation of isobutane and / or isopentane in the presence of at least one olefin containing from 2 to 6 carbon atoms per molecule, preferably 3 to 6 carbon atoms per molecule.
机译:本发明涉及一种催化剂,该催化剂包含有机或无机多孔载体,优选二氧化硅,以及包含化合物b(oso2 cf3)3和选自硫酸(h2)和so4形成的组中的至少一种酸的相酸。三氟甲磺酸(cf3·so3·h),所述载体已被酸相浸渍,所述催化剂基本上由平均直径为0.1至150μm的颗粒组成,所述催化剂的特征在于所述酸阶段包括:& br>-从0.1到70重量%的化合物b(oso2 cf3)3; & br />-0至90%(重量)的h2 so4; & br />-在CF3 SO3的0至90%重量之间。 &本发明还涉及在至少一种每分子含2至6个碳原子,优选每分子3至6个碳原子的烯烃的存在下,催化剂在异丁烷和/或异戊烷的催化烷基化中的制备和用途。分子。

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