首页> 外国专利> PRETREATMENT OF CATALYST FOR PRODUCING BISPHENOL A AND PRODUCTION OF BISPHENOL A HAVING STABLE HUE

PRETREATMENT OF CATALYST FOR PRODUCING BISPHENOL A AND PRODUCTION OF BISPHENOL A HAVING STABLE HUE

机译:制备具有稳定色相的双酚A的催化剂的预处理和双酚A的生产

摘要

PROBLEM TO BE SOLVED: To provide a method for producing bisphenol A which has a stable hue at high temperature and is not discolored, and to provide a method for preliminarily treating a sulfonic acid type ion exchange resin used as a catalyst for the above method. ;SOLUTION: This method for preliminarily treating a catalyst for producing bisphenol A comprises charging a sulfonic acid type ion exchange resin as the catalyst into a reactor, washing the sulfonic acid type ion exchange resin with water until the pH of the washing drain becomes 6 or larger, and subsequently washing the sulfonic acid type ion exchange resin with phenol until the released sulfonic acid concentration (converted into paratoluenesulfonic acid) in the washing drain becomes 2 wt.ppm or smaller. The method for producing the bisphenol A having a stable hue comprises reacting phenol with acetone in the coexistence of the pretreated catalyst for producing the bisphenol A and an alkyl mercaptan as an auxiliary catalyst.;COPYRIGHT: (C)2000,JPO
机译:解决的问题:提供一种在高温下具有稳定的色相且不会变色的双酚A的制备方法,并提供一种用于上述方法的催化剂的磺酸型离子交换树脂的初步处理方法。 ;解决方案:这种用于生产双酚A的催化剂的初步处理方法包括将磺酸型离子交换树脂作为催化剂装入反应器中,用水洗涤磺酸型离子交换树脂,直到洗涤排液的pH达到6或。然后,用苯酚洗涤磺酸型离子交换树脂,直到洗涤排水管中释放的磺酸浓度(转换为对甲苯磺酸)为2 wt.ppm或更小。具有稳定色相的双酚A的制备方法包括使苯酚与丙酮在用于制备双酚A的预处理催化剂与作为辅助催化剂的烷基硫醇共存下进行反应。版权所有:(C)2000,JPO

著录项

  • 公开/公告号JP2000143565A

    专利类型

  • 公开/公告日2000-05-23

    原文格式PDF

  • 申请/专利权人 IDEMITSU PETROCHEM CO LTD;

    申请/专利号JP19980322187

  • 发明设计人 IWAHARA MASAHIRO;

    申请日1998-11-12

  • 分类号C07C39/16;B01J31/10;B01J37/06;C07B61/00;C07C37/20;

  • 国家 JP

  • 入库时间 2022-08-22 02:00:31

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