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Resin composition for packaging applications, especially bottle production, contains polyethylene isophthalate, polyethylene terephthalate, chain-branching agent and nucleating agent

机译:用于包装应用(尤其是瓶生产)的树脂组合物包含聚间苯二甲酸乙二醇酯,聚对苯二甲酸乙二醇酯,链支化剂和成核剂

摘要

A resin composition (RC) based on (A) 1-30 wt% polyisophthalic acid diester and (B) 70-99 wt% polyterephthalic acid diester also contains (C) 250-5000 ppm chain-branching agent and (D) 50-3000 ppm nucleating agent. Independent claims are also included for:- (1) a process for the production of RC by mixing 8-20% polyethylene isophthalate (PEI), 80-92% polyethylene terephthalate (PET), 250-5000 ppm (C), 1-2% diethylene glycol or its dimethyl ether and catalyst(s) based on cobalt manganese and/or antimony in a continuous or discontinuous reactor, reacting to a homogeneous PEI/PET composition (optionally with removal of volatiles under reduced pressure), stabilizing with a phosphorus-containing stabilizer and optionally polymerizing in the solid state; (2) a similar process in which the PEI and PET are replaced by isophthalic acid and terephthalic acid (or their non-polymeric diesters) together with sufficient diol for complete reaction with these acids; (3) containers made from this RC.
机译:基于(A)1-30 wt%的聚间苯二甲酸二酯和(B)70-99 wt%的聚对苯二甲酸二酯的树脂组合物(RC)还包含(C)250-5000 ppm的支链剂和(D)50- 3000 ppm成核剂。还包括以下方面的独立权利要求:-(1)通过混合8-20%的聚间苯二甲酸乙二醇酯(PEI),80-92%的聚对苯二甲酸乙二醇酯(PET),250-5000 ppm(C),1-在连续或不连续的反应器中,使用2%二甘醇或其二甲醚和基于钴锰和/或锑的催化剂,与均质PEI / PET组合物反应(可选在减压下除去挥发物),并通过含磷稳定剂,并可选地以固态聚合; (2)类似的方法,其中PEI和PET被间苯二甲酸和对苯二甲酸(或它们的非聚合二酯)以及足够的二醇替代以与这些酸完全反应; (3)使用此RC制造的容器。

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