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Crankcase lubricant for modern heavy duty diesel and gasoline fueled engines

机译:现代重型柴油和汽油发动机的曲轴箱润滑剂

摘要

A lubricating oil having an ashless nitrogenous TBN source together with ash containing detergent having a TBN in excess of 100, a source of magnesium, and metal dihydrocarbyl dithiophosphate with predominantly or exclusively secondary hydrocarbyl groups is described. It comprises a major amount of an oil of lubricating viscosity having a sulfated ash content between 0.35 and 2 mass percent and A) a nitrogenous TBN source selected from the group consisting of ashless nitrogen containing dispersants, ashless nitrogen containing dispersant viscosity modifiers, oil soluble aliphatic, oxyalkyl, or arylalkyl amines and mixtures thereof; B) a metal salt of an oil soluble acid having a TBN in excess of 100; C) at least 500 ppm (mass) magnesium; and D) at least one metal dihydrocarbyl dithiophosphate. The nitrogenous TBN source provides at least about 1.5 TBN to the finished lubricant. The metal salt of an oil soluble acid provides at least about 40% of the total TBN of the composition. At least 50 mole per cent of the hydrocarbyl groups on the dithiophosphate are secondary. Overbased magnesium sulfonate may be used as the metal salt of an oil soluble sulfonic acid having a TBN in excess of 100 and the additive providing at least 500 ppm (mass) magnesium. The lubricant may be free of aromatic amines having at least two aromatic groups attached directly to the nitrogen. It may have at least 100 ppm (mass) boron and at least 1000 ppm (mass) phosphorous. The boron-to- nitrogen ratio is at least 0.1.
机译:描述了一种润滑油,其具有无灰的含氮TBN源以及含灰分的TBN超过100的去污剂,镁源以及具有主要或仅具有仲烃基的金属二烃基二硫代磷酸酯。它包含大量润滑粘度的硫酸盐灰分含量在0.35%至2质量%之间的油,以及A)含氮TBN源,选自无灰含氮分散剂,无灰含氮分散剂粘度调节剂,油溶性脂肪族,氧烷基或芳烷基胺及其混合物; B)TBN超过100的油溶性酸的金属盐; C)至少500 ppm(质量)镁; D)至少一种金属二烃基二硫代磷酸酯。含氮TBN源为成品润滑剂提供至少约1.5 TBN。油溶性酸的金属盐占组合物总TBN的至少约40%。二硫代磷酸酯上的至少50摩尔%的烃基是仲的。高碱性磺酸镁可用作具有TBN超过100的油溶性磺酸的金属盐,并且该添加剂提供至少500 ppm(质量)的镁。润滑剂可以不含具有至少两个直接连接到氮上的芳族基团的芳族胺。它可能含有至少100 ppm(质量)的硼和至少1000 ppm(质量)的磷。硼氮比至少为0.1。

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