Fluorochemical composition comprising a urethane comprising a fluorescent glass element roche mixture from the oligomer and a hydrophilic segment substrates spots removed end properties in order to impart

摘要

A method for preparing a fluorochemical composition comprising a polyurethane by reacting: (A) fluorochemical oligomer of formula (I): MfmMn-Q1-T1, wherein: MfmMn represents fluorochemical oligomer comprising m units derived from fluorinated monomer and n units derived from fluorine-free monomer and wherein the fluorinated monomers and fluorine-free monomers may be the same or different; m represents a value of 2 to 40; n represents a value of 0 to 20; T1 is -OH or -NH2; Q1 and T1 together represent the organic residue obtained by removing a hydrogen atom from a chain transfer agent that is functionalized with T1; (B) difunctional compound capable of reacting with an isocyanate; (C) monofunctional compound capable of reacting with an isocyanate and comprising a poly(oxyalkylene) group with (D) triisocyanate. Substrates treated with fluorochemical compositions prepared according to the method, have good stain release properties, particularly for oily stains and water based stains such as wine, tea and coffee.