Epoxy basic content chemical compound, hydroxy carbonyl compound or hydroxy carbonyl compound arukirushiriru or production manner null of arirushiriru

摘要

PURPOSE: To obtain the subject compound under mild condition in high yield by reacting a compound having double bond with an oxygencontaining gas in the presence of a transition metal compound and an metal compound. ;CONSTITUTION: An epoxy-containing compound of formula IV or hydroxycarbonyl compound of formula V or formula VI can be produced by reacting a compound having double bond, e.g. an olefin of formula II (R⁵ and R⁶ are H, alkyl or aryl; R⁷ and R⁸ are H, alkyl, alkenyl, aryl, etc.) or an enolate of formula III (R⁹ and R¹⁰ are H, alkyl or aryl; R¹¹ is H, alkyl, alkoxy, etc.; R¹² to R¹⁴ are alkyl or aryl) with an oxygen-containing gas at 10-180C (preferably 30-150C) in the presence of a compound containing transition metal (preferably a compound containing Co, Mn or Fe) and a compound of formula I (R¹ and R² are H, OH, alkoxy, siloxy, alkyl, etc.; R³ and R⁴ are H, alkyl, aryl, silyl, etc.).;COPYRIGHT: (C)1994,JPO&Japio