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New lithium organic borate compound, non-aqueous electrolyte using organic borate compound and lithium secondary battery

机译:新型有机硼酸锂化合物,使用有机硼酸化合物的非水电解质和锂二次电池

摘要

PROBLEM TO BE SOLVED: To provide an organic borate compound which has high solubility in a solvent with low permittivity and realizes high conductivity, a nonaqueous electrolyte in which the organic borate compound is dissolved, a lithium secondary battery having an improved stability at high temperature, electrical equipment in which a protection circuit may be omitted and other uses. SOLUTION: The organic borate compound is represented by formula (1) [wherein, X is Li, a quaternary ammonium group, or a quaternary phosphonium group; R1, R2, R3 and R4 are each independently a 1-4C halogenated alkyl group, a trifluoromethyl group, or a pentafluoroethyl group.]. The lithium secondary battery using the organic borate compound shows low decrease in recovery capacity at high temperature, and can be used in protection-circuit-free electrical equipment and for other uses.
机译:解决的问题:提供一种在低介电常数的溶剂中具有高溶解度并且实现高导电性的有机硼酸盐化合物,溶解有该有机硼酸盐化合物的非水电解质,在高温下具有改善的稳定性的锂二次电池,可以省略保护电路的电气设备以及其他用途。解决方案:有机硼酸盐化合物由式(1)表示[其中X为Li,季铵基或季phospho基; R1,R2,R3和R4分别独立地为1-4C卤代烷基,三氟甲基或五氟乙基。使用有机硼酸盐化合物的锂二次电池在高温下显示出较低的恢复能力降低,并且可以用于无保护电路的电气设备中以及用于其他用途。

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