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CHEMICAL PRODUCTS SUITABLE AS COCATALYSTS, THEIR PREPARATION AND THEIR USE IN CATALYST SYSTEMS FOR PREPARING POLYOLEFINS

机译:适用作助催化剂的化学制品,其制备方法及其在制备聚烯烃的催化剂体系中的用途

摘要

title: CHEMICAL PRODUCTS SUITED FOR USE AS CO-CATALYSTS, METHOD FOR THE PREPARATION THEREOF AND THEIR USE IN CATALYST SYSTEMS FOR PRODUCING POLYOLEFINSabstract: the invention relates to chemical products which are suited for use as co-catalysts and which can be obtained byreacting a compound of formula (I), M[err]R[err]R[err](R[err]with a compound of furmula (II), (R[err]X)[err][err]. In formula (I) [err]and R[err] are the same or different and represent a hydrogen atom, C[err]-C[er] alkyl, C[err]-C[err] alkyl halide, C[err]-C[err] aryl, C[err]-C[err] aryl halide, C[err]-C[err] arylalkyl, C[err]-C[err] arylalkyl halide, C[err]-C[err] alkylaryl or C[err]-C[err] alkylaryl halide; M[err] represents an element of the second or third main group of the periodic table of elements, and; m equals 0 or 1, whereby m is equal to I when M' represents an element of the third main group, and m is equal to 0 when M' represents an element of the second main group. In formula (11), substituents R[err]X, which contain hetero atoms, is located on a base body G, and: groups R[err] are the same or different and represent hydrogen, C[err]-C[err] alkyl, C[err]-C[err] alkyl halide, C[err]-C[err] aryl, C[err]-C[err] aryl halide, C[err]-C[err] arylalkyl, C[err]-C[err] arylalkyl halide, C[err] alkylaryl or C[err]-C[err] alkylaryl halide; X represents an element of the fourth, fifth or sixth main group of the periodic table of elements; G represents at least bivalent C[err]-C[err] alkylene, C[err]-C[err] alkylene halide, C[err]-C[err] alkylenoxy, C[err]-C[err] arylene, C[err]-C[err] arylene halide, C6-C40 arylenoxy, C[err]-C[err] arylalkylene, C[err]-C[err] arylalkylene halide, C[err]-C[err] alkylarylene, C[err]-C[err] alkylarylene halide; M[err] represents an element of the fourth, fifth or sixth main group of the periodic table of elements; R[err] and R[err], independent of one another, are the same or different and represent a hydrogen atom, C[err]-C[err] alkyl, C[err]-C[err] alkoxy, C[err]-C[err] alkenyl, C[err]-C[err] arylalkyl, C[err]-C[err] alkylaryl, C[err]-C[err] aryloxy, C[err]-C[err] alkyl halide; q is a whole number ranging from 2 to 100, and; g is a whole number ranging from 1 to 100. The invention also relates to a method for preparing the inventive chemical products, and to their use in catalyst systems for producing polyolefins.[err][err]
机译:标题:用作共催化剂的化学产品,其制备方法及其在生产聚烯烃的催化剂体系中的用途摘要:本发明涉及适合用作助催化剂的化学产物,其可以通过以下方法获得:使式(I)的化合物M [err] R [err] R [err](R [err]与式(II)的化合物(R [err] X)[err] [err]反应。公式(I)[错误]和R [err]相同或不同,表示氢原子,C [err] -C [er]烷基,C [err] -C [err]烷基卤,C [err] -C [err]芳基, C [err] -C [err]芳基卤,C [err] -C [err]芳基烷基,C [err] -C [err]芳基烷基卤,C [err] -C [err]烷基芳基或C [err] -C [err]烷基芳基卤; M [err]代表第二个元素或元素周期表的第三主要组;以及m等于0或1,因此当M'表示元素时m等于I在第三主基团中,当M′代表第二主基团的元素时,m等于0。在式(11)中,取代基含有杂原子的R X X位于基体G上,并且:基团R R相同或不同,表示氢,C [err] -C [err]烷基,C [err] -C [err]烷基卤,C [err] -C [err]芳基,C [err] -C [err]芳基卤,C [err] -C [err]芳基烷基,C [err] -C [err]芳基烷基卤,C [err]烷基芳基或C [err] -C [err]烷基芳基卤化物; X代表元素周期表的第四,第五或第六主族的元素; G代表至少二价C [err] -C [err]亚烷基,C [err] -C [err]亚烷基卤,C [err] -C [err]亚烷氧基,C [err] -C [err]亚芳基,C [err ] -C [err]亚芳基卤化物,C6-C40芳氧C [err] -C [err]芳基亚烷基,C [err] -C [err]芳基亚烷基卤,C [err] -C [err]烷基亚芳基,C [err] -C [err]烷基亚芳基卤; M [err]代表元素周期表的第四,第五或第六主族; R [err]和R [err]彼此独立,相同或不同,代表氢原子,C [err] -C [err]烷基,C [err] -C [err]烷氧基,C [err] -C [err]烯基,C [err] -C [err]芳烷基,C [err] -C [err]烷基芳基,C [err] -C [err]芳氧基,C [err] -C [err]卤代烷; q是2到100的整数,并且g是1至100的整数。本发明还涉及本发明涉及制备本发明化学产品的方法,以及它们在生产聚烯烃的催化剂体系中的用途。[呃][呃]

著录项

  • 公开/公告号SG93439A1

    专利类型

  • 公开/公告日2003-03-18

    原文格式PDF

  • 申请/专利权人 NOVOLEN TECHNOLOGY HOLDINGS C.V.;

    申请/专利号SG2002072395

  • 发明设计人 SCHOTTEK JÖRG;

    申请日2001-05-19

  • 分类号C07F5/00;

  • 国家 SG

  • 入库时间 2022-08-22 00:00:57

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