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Ceramic composition, composite material, composite material production method, porous body, oxygen separator, and chemical reactor

机译:陶瓷组合物,复合材料,复合材料的制造方法,多孔体,氧分离器和化学反应器

摘要

A ceramic composite with a mixed conducting oxide that has perovskite type crystal structure of {Ln1−aAa}{BxB′yB″z}O(3−δ) where a, x, y, and z are within the range of 0.8≦a≦1, 0x, 0y≦0.5, 0≦z≦0.2, 0.98≦x+y+z≦1.02, and δ denotes a value that is determined so as to meet a charge neutralization condition. A denotes a combination of one or more kinds of elements selected out of Ba, Sr, and Ca. B denotes a combination of one or more kinds of elements selected out of Co, Fe, Cr, and Ga, the combination always containing Fe or Co. B′ denotes a combination of one or more kinds of elements selected out of Nb, Ta, Ti, and Zr, the combination always containing Nb or Ta. The present invention is also directed to a mixed conducting oxide and a ceramic composite. The mixed conducting oxide is of formula AFexO(3−δ). A is selected out of Ba, Sr, and Ca, and is within the range of 0.98≦x≦1.02, and δ denotes a value determined so as to meet the charge neutralization conditions.
机译:具有钙钛矿型晶体结构{Ln 1-a A a } {B x B'< Sub> y B” z } O (3-δ)其中a,x,y和z在0.8≦a≦1的范围内,0 <x,0 <y≤0.5,0≤z≤0.2,0.98≤x + y +z≤1.02,并且δ表示被确定为满足电荷中和条件的值。 A表示从Ba,Sr和Ca中选择的一种或多种元素的组合。 B表示从Co,Fe,Cr和Ga中选出的一种或多种元素的组合,该组合总是包含Fe或Co。B'表示从Nb,Ta,D中选择的一种或多种元素的组合。 Ti和Zr,该组合始终包含Nb或Ta。本发明还涉及混合的导电氧化物和陶瓷复合材料。混合导电氧化物的分子式为AFe x O (3-δ)。 选自Ba,Sr和Ca,并且在0.98≤x≤1.02的范围内,并且δ表示确定为满足电荷中和条件的值。

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