Method for Control of Pest insects of the orders Lepidoptera, Homoptera, Hemiptera, Thysanoptera Coleoptera and Antranilamida using composite and composite Intermediate in the synthesis of such compounds

摘要

Method for Control of Pest insects of the orders led the doctor out, Homoptera, Hemiptera, Thysanoptera and Coleoptera, which comprises contacting the insects or Their Environments as artropodicida with an effective amount of a compound of formula (1), a n - Oxide or Salt acceptable for use in Agriculture where a and B are the same regardless o or s, R1 is H, alkyl C1 - 6,Alcoxicarbonilo C2 or C2 - 6 - 6 alquilcarbonilo; R2 is H, or C1 - 6 alkyl; R3 is H, alkyl - 6 - C1, C2 or C3 - 6 6 alquenilo, optionally substituted cycloalkyl, each with one or more substituents selected from the group formed by NO2, CN, halogen, Hydroxy, c1-4 c1-4 alkyl, alkoxy, c1-4 naloalcoxi 4 Alquiltio C1, C1 -, - 4 - 4 alquilsulfonilo alquilsulfinilo, C1, C2 - 6 alcoxicarbonilo,Alquilcarbonilo C2 - C3 - 6, 6 trialquilsililo, phenyl, phenoxy, heteroaromatic Rings of 5 members, and heteroaromatic Rings of six members, where each phenyl, phenoxy, ring heteroaromu00e1tico 5 members, and six member Ring heteroaromu00e1tico optionally replaced with between one and three of its Tituyentes independently selected from the group consisting of c1-4 alkyl, C2 - 4 alquenilo,Alquinilo C2 - C3 - 4, 6 - 4 haloalquilo cycloalkyl, C1, C2 - 4 - 4 haloalquinilo haloalquenilo, C2, C3 - 6 halocicloalquilo, halogen, CN, NO2, c1-4 alkoxy, C1 - 4 - 4 Alquiltio haloalcoxi, C1, C1 - 4 - 4 alquilsulfonilo alquilsulfinilo, C1, C1 - 4 alquilamino, C2 - 4 - 6 cicloalquilamino dialquilamino, C3, C4 (alkyl) - 8 (cicloalquil) amino - 4alquilcarbonilo C2, C2, C2 - 6 - 6 alcoxicarbonilo, alquilaminocarbonilo,C3 and C3 - 6 - 8 dialquilaminocarbonilo trialquilsililo, c1-4 alkoxy, alquilamino C1 - C2 - 4, 6 - 8 dialquilamino cicloalquilamino, C3, C2 or C2 alcoxicarbonilo - 6, 6 - alquilcarbonilo; R4 is H, alkyl C1 - C2 - 6, 6 - 6 alquinilo alquenilo, C2, C3 cycloalkyl - 6 6 haloalquilo, C1 -, CN, c1-4 alkoxy, halogen, C1 - 4 Loalcoxi, or NO2; R5 is H, alkyl C1 C1 - 6, 6 - 4 - haloalquilo alkoxyalkyl esters, C1, C1 - 4 hidroxialquilo,Co2r10 R10, C (o) C (o), nr10r11 c1-4 alkoxy, halogen, c1-4 haloalcoxi, nr10r11, N (R11) C (o) n (co2r10 R10, R11) or s (OR) nr12, R6 is H, alkyl C1 C1 - 6, 6 - haloalquilo, halogen, CN, c1-4 alkoxy or haloalcoxi c1-4 alkyl; R7 is C1 - C2 - 6, 6 - 6alquinilo alquenilo, C2, C3 - 6 - 6 haloalquilo cycloalkyl, C1, C2 - 6 Haloalquenilo, C2 or C3 - 6 - 6 haloalquinilo halocicloalquilo R7 is a phenyl Ring; or,A heteroaromu00e1tico benzyl ring, a Ring of 5 or 6 members, a naphthyl Ring system or a system of heterobicu00edclicos FUSED Aromatic Rings of 8, 9, or 10 members, each Ring or Ring System optionally substituted with 1 to 3 independently Selected substituents Relationships between R9 R8 is H, alkyl C1, C1 - 6, 6 - haloalquilo, c1-4 alkoxy, halogenOr haloalcoxi R9 c1-4; each is independently c1-4 alkyl, C2 - 4 - 4 alquinilo alquenilo, C2, C3 - 6 - 4 haloalquilo cycloalkyl, C1, C2 - 4 - 4 haloalquinilo haloalquenilo, C2, C3 - 6 halocicloalquilo, halogen, CN, NO2, c1-4 alkoxy, c1-4 haloalcoxi, c1-4 Alquiltio, c1-4 alquilsulfinilo, c1-4 alquilsulfo Nile, alquilamino C1 - C2 - 4, 6 - 8 dialquilamino cicloalquilamino, C3, C4 - 8 (cicloalquil (alkyl) amino)Alquilcarbonilo C2 C2 - 4, 6 - 4 aquilaminocarbonilo alcoxicarbonilo, C2, C3 and C3 - 6 - 8 dialquilaminocarbonilo R10 trialquilsililo; c1-4 alkyl is H, or C1 - 4 haloalquilo; R11 is H or a c1-4 alkyl; R12 is c1-4 alkyl or c1-4 haloalquilo; and N is 0, 1, or 2.Also described is a compound of benzoxazinona, Intermediate in the synthesis of compounds of formula (1), which responds to the formula (2) where r is H, alkyl C1 - C2 - 6, 6 - 6 alquinilo alquenilo, C2, C3 - 6 - 6 haloalquilo cycloalkyl, C1, C1 CN, halogen - 4 haloalcoxi c1-4 alkoxy, or NO2; R 5 - 6 C1 is H, alkyl, haloalquilo C1 C1 - 6, - 4 - 4 hidroxialquilo alkoxyalkyl esters, C1, C (o) co2r10, R10,(c) nr10r11 c1-4 alkoxy, halogen, c1-4 haloalcoxi, nr10r11, N (R11) C (o) n (co2r10 R10, R11) or s (o) h R6, R12; C1 - 6 - 6 haloalquilo C1 alkyl, halogen, CN, c1-4 alkoxy haloalcoxi or c1-4 alkyl; R7 is C1 - C2 - 6, 6 - 6 alquinilo alquenilo, C2, C3 - 6 - 6 haloalquilo cycloalkyl, C1, C2 - 6 haloalquenilo, Haloalquinilo C2 or C3 - 6, 6 - or halocicloalquilo; R7 is a benzyl phenyl ring, a ring,A ring heteroaromu00e1tico of 5 or 6 members, a system or a naphthyl Rings FUSED Aromatic Ring System heterobicu00edclicos 8, 9 or 10 members, each Ring or Ring System optionally substituted with between 1 and 3 substituents selected from R9 R8 independently; C1 - 6 IS h, alkyl, halogen, haloalquilo C1 - 6,C1-4 alkoxy or c1-4 haloalcoxi R9; each is independently c1-4 alkyl, C2 - 4 - 4 alquinilo alquenilo, C2, C3 - 6 - 4 haloalquilo cicloalquil, C1, C2 - 4 - 4 haloalquinilo haloalquenilo, C2, C3 - 6 halocicloalquilo, halogen, CN, NO2, c1-4 alkoxy 4 haloalcoxi C1, C1 -, - 4 - 4 alquilsulfinilo Alquiltio, C1, C1 - 4 Alquilsulfonilo - 4 alquilamino C1, C2, C3 dialquilamino - 8, - 6 cicloalquilamino,C4 - 8 (cicloalquil) (alkyl) amino alquilcarbonilo C2, C2 - 4 - 6, 6 - alquilaminocarbonilo alcoxicarbonilo, C2, C3 and C3 - 6 - 8 dialquilaminocarbonilo R10 trialquilsililo; c1-4 alkyl is H, or C1 - 4 haloalquilo; R11 is H, or C1 - 4 R12 is c1-4 alkyl; haloalquilo or c1-4 alkyl; n is 0, 1 or 2.