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Supported solid catalyst for the polymerisation of conjugated dienes, process for preparing the same and polymerisation process using the catalyst
Supported solid catalyst for the polymerisation of conjugated dienes, process for preparing the same and polymerisation process using the catalyst
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机译:用于共轭二烯聚合的负载型固体催化剂,其制备方法和使用该催化剂的聚合方法
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摘要
Catalyst for the polymerization of conjugated dienes which comprises the reaction product of a complex of a rare earth metal with an aluminum halide in an aromatic solvent and a solid support comprising at least one metal oxide. The complex is of formula M(Ar)(AlX4)3, M = a rare earth metal with atomic number 57-71 in the periodic table; Ar = an aromatic hydrocarbon solvent; X = F, Cl, Br, I An Independent claim is included for a method of polymerization of conjugated dienes (preferably 1,3-butadiene and/or isoprene) in inert hydrocarbon solvent using the claimed catalyst and trialkylaluminum or dialkylaluminum chloride activator.
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机译:用于共轭二烯聚合的催化剂,其包括在芳族溶剂中稀土金属与卤化铝的配合物与包含至少一种金属氧化物的固体载体的反应产物。该络合物的分子式为M(Ar)(AlX4)3,M =元素周期表中原子序数为57-71的稀土金属; Ar =芳香烃溶剂; X = F,Cl,Br,I使用所要求保护的催化剂和三烷基铝或氯化二烷基铝,在惰性烃溶剂中聚合共轭二烯(优选1,3-丁二烯和/或异戊二烯)的方法包括独立权利要求。
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