1.the application of complex of transition metal with at least one u0430u0437u043eu0442u0441u043eu0434u0435u0440u0436u0430u0449u0438u043c u043fu043eu043bu0438u0434u0435u043du0442u0430u0442u043du044bu043c u043bu0438u0433u0430u043du0434u043eu043c as catalyst u043eu0442u0431u0435u043bu0438u0432u0430u043du0438u00a0 u0434u043bu00a0 activation perec u0438u0441u043du044bu0445 compounds or oxygen, where the compound u00a0u0432u043bu00a0u0435u0442u0441u00a0 mono - or u043fu043eu043bu0438u00a0u0434u0435u0440u043du044bu043c, transition metal (m) u043fu0440u0435u0434u0441u0442u0430u0432u043bu00a0u0435u0442 a manganese, iron, cobalt or copperand at least one of the present nitrogen u043fu043eu043bu0438u0434u0435u043du0442u0430u0442u043du044bu0445 u043bu0438u0433u0430u043du0434u043eu0432 (l) has the general formula (i);where in the u043fu0440u0435u0434u0441u0442u0430u0432u043bu00a0u0435u0442 a u043cu043eu0441u0442u0438u043au043eu0432u044bu0439 fragment from the u0440u00a0u0434u0430 containing;r1 and r2 independently u043fu0440u0435u0434u0441u0442u0430u0432u043bu00a0u044eu0442 a radical of the u0440u00a0u0434u0430 containing hydrogen, linear, cyclic or elaborate u0430u043bu043au0438u043b, u0433u0435u0442u0435u0440u043eu0430u043bu043au0438u043b, u0430u0440u0438u043b, u0433u0435u0442u0435u0440u043eu0430u0440u0438 l u0430u0440u0438u043bu0430u043bu043au0438u043b and u0433u0435u0442u0435u0440u043eu0430u0440u0438u043bu0430u043bu043au0438u043b;;r3 and r4 independently of each other u043fu0440u0435u0434u0441u0442u0430u0432u043bu00a0u044eu0442 a radical of the u0440u00a0u0434u0430 containing u0430u0440u0438u043b, u0433u0435u0442u0435u0440u043eu0430u0440u0438u043b, u0430u043bu043au043eu043au0441u0438u0433u0440u0443u043fu043fu0443, u0430u0440u0438u043bu0430u043bu043au043eu043au0441u0438u0433u0440u0443u043fu043fu0443, u0433u0435u0442u0435u0440u043eu0430u0440u0438u043bu0430u043bu043au0438u043b and u0430u0440u0438u043bu0430u043bu043au0438u043b, dg e organic radicals r1 to r4 may be u0437u0430u043cu0435u0449u0435u043du043du044bu043cu0438,;the c = n group of r1 - r3 and / or r2 - c = n - r4 independently of each other u043fu0440u0435u0434u0441u0442u0430u0432u043bu00a0u044eu0442 a 5 - 7 - u0447u043bu0435u043du043du044bu0435 u0433u0435u0442u0435u0440u043eu0446u0438u043au043bu0438u0447u0435u0441u043au0438u0435 n - or n - u0433u0435u0442u0435u0440u043eu0430u0440u043eu043cu0430u0442u0438u0447u0435u0441u043au0438u0435 rings, which additionally can take one or two others u0433u0435u0442u0435u0440u043eu0430u0442u043eu043cu0430 of u0440u00a0u0434u0430 containing oxygen (o), nitrogen (n) and sulfur (s), and may be u0437u0430u043cu0435u0449u0435u043du043du044bu043cu0438;;u043cu043eu0441u0442u0438u043au043eu0432u044bu0439 fragment;u043fu0440u0435u0434u0441u0442u0430u0432u043bu00a0u0435u0442 a 5 - 6 - u0447u043bu0435u043du043du0443u044e u043du0435u043eu0431u00a0u0437u0430u0442u0435u043bu044cu043du043e u0437u0430u043cu0435u0449u0435u043du043du0443u044e u0446u0438u043au043bu043eu0430u043bu043au0438u043bu044cu043du0443u044e or u0433u0435u0442u0435u0440u043eu0446u0438u043au043bu043eu0430u043bu043au0438u043bu044cu043du0443u044e group with a u0442u0440u0435u043cu00a0 u0433u0435u0442u0435u0440u043eu0430u0442u043eu043cu0430u043cu0438 of u0440u00a0u0434u0430 containing nitrogen (n), the oxygen (o) and sulfur (s) and u043cu043eu0441u0442u0438u043au043eu0432u044bu0439 fragment;u043fu0440u0435u0434u0441u0442u0430u0432u043bu00a0u0435u0442 a 5 - 7 - u0447u043bu0435u043du043du044bu0439 u043du0435u043eu0431u00a0u0437u0430u0442u0435u043bu044cu043du043e u0437u0430u043cu0435u0449u0435u043du043du044bu0439 u0446u0438u043au043bu043eu0430u043bu0438u0444u0430u0442u0438u0447u0435u0441u043au0438u0439, aromatic, u0433u0435u0442u0435u0440u043eu0446u0438u043au043bu0438u0447u0435u0441u043au0438u0439 or u0433u0435u0442u0435u0440u043eu0430u0440u043eu043cu0430u0442u0438u0447u0435u0441u043au0438u0439 radical, where z is selected from the u0440u00a0u0434 a containing oxygen (o) - n (r-6) -, - n = or - c (he) 2 - and group g2 may contain one or two u0433u0435u0442u0435u0440u043eu0430u0442u043eu043cu0430 of u0440u00a0u0434u0430 containing oxygen (o), nitrogen (n) and sulfur (s), and / or u0437u0430u043cu0435u0441u0442u0438u0442u0435u043b and;;r5 and r-6 were independent from each other and may be u0437u043du0430u0447u0435u043du0438u00a0 according to the definition of u0434u043bu00a0 r1, where r1 is a deputy in the r-6, g1 and g2 can be selected from the u0440u00a0u0434u0430 containing functional were and u043du0435u0444u0443u043du043au0446u0438u043eu043du0430u043bu044cu043du044bu0435 vice, such as, in particular, unprofor, SO3u043d, NH2, n + (u0430u043bu043au0438u043b) 4, so3 -, u0441u043e3 -, cl, f, (c1 - c4) u0430u043bu043au043eu043au0441u0438u0433u0440u0443u043fu043fu0430 (c1 - c4) u0430u043bu043au0438u043b, u0444u0435u043du0438u043b, benzyl, u043fu0438u0440u0438u0434u0438u043b and 2 - u043fu0438u0440u0438u0434u0438 u043bu043cu0435u0442u0438u043b;;and where u043bu0438u0433u0430u043du0434u044b, which u043cu043eu0441u0442u0438u043au043eu0432u044bu0439 fragment in a u043fu0440u0435u0434u0441u0442u0430u0432u043bu00a0u0435u0442;deleted, if u043au043eu043bu044cu0446u0435u0432u0430u00a0 system u043eu0431u0440u0430u0437u043eu0432u0430u043du043du0430u00a0 of r1 - c = n - r3 and / or r2 - c = n - r4 designates the ring than u043du0435u043eu0431u00a0u0437u0430u0442u0435u043bu044cu043du043e u0437u0430u043cu0435u0449u0435u043du043du043eu0433u043e 1.3 - u043eu043au0441u0430u0437u043eu043bu0438u043d - 2 - silt, or r3 and r4 exce u0447u043du044b from u0433u0435u0442u0435u0440u043eu0430u0440u0438u043bu0430, u0433u0435u0442u0435u0440u043eu0430u0440u0438u043bu043cu0435u0442u0438u043bu0430, u0430u043bu043au043eu043au0441u0438u0433u0440u0443u043fu043fu044b or u0430u0440u0438u043bu043eu043au0441u0438u0433u0440u0443u043fu043fu044b.;2. application of u043eu0442u043bu0438u0447u0430u044eu0449u0435u0435u0441u00a0 1, so that u0438u0441u043fu043eu043bu044cu0437u0443u0435u0442u0441u00a0 complex with u043bu0438u0433u0430u043du0434u043eu043c, which u043cu043eu0441u0442u0438u043au043eu0432u044bu0439 fragment in common formula;u0432u043bu00a0u0435u0442u0441u00a0 u0433u0435u0442u0435u0440u043eu0446u0438u043au043bu0438u0447u0435u0441u043au0438u043c n - or n - u0433u0435u0442u0435u0440u043eu0430u0440u043eu043cu0430u0442u0438u0447u0435u0441u043au0438u043c and, in particular, is selected from the u0440u00a0u0434u0430 containing pyridine - 2,6 - u0434u0438u0438u043b, 2.5 - u0434u0438u0438u043b pyrrole, imidazole - 2.5 - u0434u0438u0438u043b, piperidine - 2.6 - u0434u0438u0438u043b, 3.5 - u0434u0438u0438u043b morpholine, pyrrolidine - 2.5 - u0434u0438u0438u043b, 1,3,5 - u0442u0440u0438u0430u0437u0438u043d - 2.6 - u0434u0438u0438u043b.;3. application of u043eu0442u043bu0438u0447u0430u044eu0449u0435u0435u0441u00a0 1, so that u0438u0441u043fu043eu043bu044cu0437u0443u0435u0442u0441u00a0 complex with u043bu0438u0433u0430u043du0434u043eu043c, in which groups of r1 - c = n - r3 and r2 - c = n - r4 u00a0u0432u043bu00a0u044eu0442u0441u00a0 identical.;4. application of u043eu0442u043bu0438u0447u0430u044eu0449u0435u0435u0441u00a0 1, so that the c = n group of r1 - r3 and / or r2 - c = n - r4 u043bu0438u0433u0430u043du0434u0430 u043fu0440u0435u0434u0441u0442u0430u0432u043bu00a0u044eu0442 a radical u043eu043au0441u0430u0437u043eu043bu0438u043d 1.3 - 2 - il.;5. application of 1, u043eu0442u043bu0438u0447u0430u044eu0449u0435u0435u0441u00a0, r1 and r2 and / or r3 and r4 u043fu0440u0435u0434u0441u0442u0430u0432u043bu00a0u044eu0442 a ring u043eu043au0441u0430u0437u043eu043bu0438u043d 1.3 - 2 - silt.;6. application of paragraph 4 or 5, u043eu0442u043bu0438u0447u0430u044eu0449u0435u0435u0441u00a0 so that one or more of the 1.3 u043eu043au0441u0430u0437u043eu043bu0438u043d - 2 -) radicals contain under four conditions, in particular, selected from the u0440u00a0u0434u0430, ods u0435u0440u0436u0430u0449u0435u0433u043e u0438u0437u043eu043fu0440u043eu043fu0438u043b, tert butyl, benzyl, 2 - u043fu0438u0440u0438u0434u0438u043bu043cu0435u0442u0438u043b.;7. application of u043eu0442u043bu0438u0447u0430u044eu0449u0435u0435u0441u00a0 1, so that the complex is of the general formula (LmMnu0445u043e] Yu0440, where l denotes the ligand according to one ap.1 - 6, m denotes a transition metal of u0440u00a0u0434u0430 containing from mn (ii) to mn (iv), fe (ii), fe (iii), co (ii), co (ii), cu (ii), and cu (ii), x denotes a coordinated neutral or u0437u0430u0440u00a0u0436u0435u043du043du044bu0439 mono - or and u043fu043eu043bu0438u0432u0430u043bu0435u043du0442u043du044bu0439 ligand u0434u043bu00a0 u043du0430u0441u044bu0449u0435u043du0438u00a0 u043bu0438u0433u0430u043du0434u043du043eu0439 scope, y denotes u043du0435u043au043eu043eu0440u0434u0438u043du0438u0440u043eu0432u0430u043du043du044bu0439 u043fu0440u043eu0442u0438u0432u043eu0438u043eu043d, which can be u0430u043du0438u043eu043du043du044bu043c orif the amount of u0430u043du0438u043eu043du043du044bu0445 u043bu0438u0433u0430u043du0434u043eu0432 in u043bu0438u0433u0430u043du0434u0435 l exceeds the amount of the valencies of atoms of metal m, may also be u043au0430u0442u0438u043eu043du043du044bu043c, m denotes an integer from 1 to 4, cha u0441u0442u043du043eu0441u0442u0438, 1 or 2, n denotes the number 1 or 2, a is zero or an integer between 1 and 8 and p is zero or an integer between 1 and 8, necessary d. u043bu00a0 u0434u043eu0441u0442u0438u0436u0435u043du0438u00a0 full compensation u0437u0430u0440u00a0u0434u0430.;8. application on p.7, u043eu0442u043bu0438u0447u0430u044eu0449u0435u0435u0441u00a0, u0438u0441u043fu043eu043bu044cu0437u0443u0435u0442u0441u00a0 complex of the general formula (Yp LMXo], in which the radicals u0441u0432u00a0u0437u0430u043du043du044bu0435 with u043cu043eu0441u0442u0438u043au043eu0432u044bu043c fragment in u043bu0438u0433u0430u043du0434u0430 l, u00a0u0432u043bu00a0u044eu0442u0441u00a0 ident u0438u0447u043du044bu043cu0438.;9. application of u043eu0442u043bu0438u0447u0430u044eu0449u0435u0435u0441u00a0 1, so that the u0430u043au0442u0438u0432u0438u0440u0443u0435u0442u0441u00a0 hydrogen peroxide or u043fu0435u0440u043eu043au0441u0438u043au0430u0440u0431u043eu043du043eu0432u044bu0435 acid having from 2 to 12 carbon atoms, (c), which may also be it formed in situ from a source of hydrogen peroxide and the activation of u0440u00a0u0434u0430 containing o - or n - u0430u0446u0438u043bu0438u0440u043eu0432u0430u043du043du044bu0435 u0430u0446u0438u043bu0438u0440u043eu0432u0430u043du043du044bu0435 u0441u043eu0435u0434u0438u043du0435u043du0438u00a0.;10. application of 1, u043eu0442u043bu0438u0447u0430u044eu0449u0435u0435u0441u00a0, complexes of transition metals u0438u0441u043fu043eu043bu044cu0437u0443u044eu0442u0441u00a0 in amount of from 0.0001 to 50 mas.%, in particular from 0.01 to 20% of the u0441u043eu0434u0435u0440u0436u0430u043du0438u00a0 u043fu0435u0440u0435u043au0438u0441u043d mas. wow u0441u043eu0435u0434u0438u043du0435u043du0438u00a0.;11. u043au043eu043cu043fu043eu0437u0438u0446u0438u00a0 whitening means u0441u043eu0434u0435u0440u0436u0430u0449u0430u00a0 u043fu0435u0440u0435u043au0438u0441u043du043eu0435 compound and transition metal complex in an amount effective u0434u043bu00a0 activation u043fu0435u0440u0435u043au0438u0441u043du043eu0433u043e u0441u043eu0435u0434u0438u043du0435 u043du0438u00a0, u043eu0442u043bu0438u0447u0430u044eu0449u0430u00a0u0441u00a0 that contains the transition metal complex is one of the u043fu043f.1 - 8.;12. u043au043eu043cu043fu043eu0437u0438u0446u0438u00a0 whitening means of p.11, u043eu0442u043bu0438u0447u0430u044eu0449u0430u00a0u0441u00a0, u043fu0435u0440u0435u043au0438u0441u043du043eu0435 compound selected from u0440u00a0u0434u0430 containing hydrogen peroxide, a source of hydrogen peroxide, in particular, u043fu0435u0440u0431u043eu0440u0430u0442 alkali metal or alkali metal percarbonate and u043fu0435u0440u043eu043au0441u0438u043au0430u0440u0431u043eu043du043eu0432u044bu0435 acid having from 2 to 6 carbon atoms, (c) or a source of hydrogen peroxide and predecessor u043fu0435u0440u043eu043au0441u0438u043au0430u0440u0431u043eu043du043eu0432u043eu0439 acid, in particular,o - or n - u0430u0446u0438u043bu0438u0440u043eu0432u0430u043du043du043eu0433u043e u0430u0446u0438u043bu0438u0440u043eu0432u0430u043du043du043eu0433u043e u0441u043eu0435u0434u0438u043du0435u043du0438u00a0, or their mixture.;13. u043au043eu043cu043fu043eu0437u0438u0446u0438u00a0 whitening the p.11, u043eu0442u043bu0438u0447u0430u044eu0449u0430u00a0u0441u00a0 that additionally contains one or more surfactants (surfactant), in particular, u043cu043eu044eu0449u0435 - u043au0442u0438u0432u043du044bu0435 surfactant.;14. u043au043eu043cu043fu043eu0437u0438u0446u0438u00a0 whitening the p.11, u043eu0442u043bu0438u0447u0430u044eu0449u0430u00a0u0441u00a0 that additionally contains fillers, in particular zeolite.;15. u043au043eu043cu043fu043eu0437u0438u0446u0438u00a0 whitening the p.11, u043eu0442u043bu0438u0447u0430u044eu0449u0430u00a0u0441u00a0, u043fu0440u0435u0434u0441u0442u0430u0432u043bu00a0u0435u0442 a u0441u043eu0441u0442u0430u0432u043bu00a0u044eu0449u0443u044e liquid, whitening or u0447u0438u0441u0442u00a0u0449u0435u0433u043e composition containing one or and several surfactants and one or more fillers.;16. u043au043eu043cu043fu043eu0437u0438u0446u0438u00a0 whitening the p.11, u043eu0442u043bu0438u0447u0430u044eu0449u0430u00a0u0441u00a0 that contains from 0.001 to 50 mas.%, in particular from 0.01 to 20 mas.% of transition metal specified in the one of the u043fu043f.1 - 8, from u0441u043eu0434u0435u0440u0436u0430u043du0438u00a0 u043fu0435u0440u0435u043au0438u0441u043du043eu0433u043e u0441u043eu0435u0434u0438u043du0435u043du0438u00a0 and u043fu0435u0440u0435u043au0438u0441u043du043eu0433u043e u0441u043eu0435u0434u0438u043du0435u043du0438u00a0 or his predecessor.
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