wherein DMP means N,N-dimethylpiperidinium (mepiquate); M means metal cation acceptable for agriculture and chosen from a series comprising sodium, potassium, magnesium, calcium, zinc, manganese or copper, hydrogen atom or NH4+; O means oxygen atom; A means chelate of complex-forming fragment bound with one boron atom and representing (lower)-alkylglycols or sugars; n and m mean similar whole numbers in the range from 1 to 6; x means a whole or fraction number in the range from 0 to 10; y means a whole or fraction number in the range from 1 to 48; z means a whole or fraction number in the range from 0 to 48; v means a whole or fraction number in the range from 0 to 24, and w means a whole or fraction number in the range from 0 to 24. Also, invention describes methods for preparing compound of the formula (I) by interaction of N,N-dimethylpiperidinium hydroxide with boric acid and/or boron-containing oxides and optionally with metal hydroxides acceptable for agriculture indicated above or electrochemical method involving interaction of N,N-dimethylpiperidinium halide in the presence of water and boric acid and in the presence metal hydroxides acceptable for agriculture by bipolar electrodialysis. Invention describes electrochemical method for preparing N,N-dimethylpiperidinium hydroxide and a suspension concentrate possessing the plant growth-regulating effect prepared by mixing N,N-dimethylpiperidinium hydroxide, boron-containing compound chosen from boric acid and borate salt with a thickening agent and water, or by mixing compound of the formula (I) with Na2B8O13 x 4 H2O, a thickening agent and water. Prepared derivatives of mepiquate borate possess the improved indices of hygroscopicity and corrosion activity.;EFFECT: improved preparing methods, valuable properties of derivatives.;22 cl, 7 tbl, 16 ex"/>
DERIVATIVES OF MEPIQUATE BORATE, METHODS FOR THEIR PREPARING, ELECTROCHEMICAL METHOD FOR PREPARING N,N-DIMETHYLPIPERIDINIUM, SUSPENSION CONCENTRATE POSSESSING PLANT GROWTH-REGULATING EFFECT
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DERIVATIVES OF MEPIQUATE BORATE, METHODS FOR THEIR PREPARING, ELECTROCHEMICAL METHOD FOR PREPARING N,N-DIMETHYLPIPERIDINIUM, SUSPENSION CONCENTRATE POSSESSING PLANT GROWTH-REGULATING EFFECT
DERIVATIVES OF MEPIQUATE BORATE, METHODS FOR THEIR PREPARING, ELECTROCHEMICAL METHOD FOR PREPARING N,N-DIMETHYLPIPERIDINIUM, SUSPENSION CONCENTRATE POSSESSING PLANT GROWTH-REGULATING EFFECT
FIELD: chemistry of metalloorganic compounds, agriculture.;SUBSTANCE: invention describes derivatives of mepiquate borate of the general formula (I): wherein DMP means N,N-dimethylpiperidinium (mepiquate); M means metal cation acceptable for agriculture and chosen from a series comprising sodium, potassium, magnesium, calcium, zinc, manganese or copper, hydrogen atom or NH4+; O means oxygen atom; A means chelate of complex-forming fragment bound with one boron atom and representing (lower)-alkylglycols or sugars; n and m mean similar whole numbers in the range from 1 to 6; x means a whole or fraction number in the range from 0 to 10; y means a whole or fraction number in the range from 1 to 48; z means a whole or fraction number in the range from 0 to 48; v means a whole or fraction number in the range from 0 to 24, and w means a whole or fraction number in the range from 0 to 24. Also, invention describes methods for preparing compound of the formula (I) by interaction of N,N-dimethylpiperidinium hydroxide with boric acid and/or boron-containing oxides and optionally with metal hydroxides acceptable for agriculture indicated above or electrochemical method involving interaction of N,N-dimethylpiperidinium halide in the presence of water and boric acid and in the presence metal hydroxides acceptable for agriculture by bipolar electrodialysis. Invention describes electrochemical method for preparing N,N-dimethylpiperidinium hydroxide and a suspension concentrate possessing the plant growth-regulating effect prepared by mixing N,N-dimethylpiperidinium hydroxide, boron-containing compound chosen from boric acid and borate salt with a thickening agent and water, or by mixing compound of the formula (I) with Na2B8O13 x 4 H2O, a thickening agent and water. Prepared derivatives of mepiquate borate possess the improved indices of hygroscopicity and corrosion activity.;EFFECT: improved preparing methods, valuable properties of derivatives.;22 cl, 7 tbl, 16 ex
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机译：领域：本发明描述了通式（I）的异丙基硼酸盐的衍生物：<图像文件=“ 00000002.GIF” he =“ 7” id =“ imag00000002” imgContent =“ undefined” imgFormat =“ GIF” wi =“ 72” />，其中DMP表示N，N-二甲基哌啶（异丙基）; M是农业上可接受的金属阳离子，选自钠，钾，镁，钙，锌，锰或铜，氢原子或NH 4 + ; O表示氧原子;指与一个硼原子结合并代表（低级）-烷基二醇或糖的形成配合物的片段的螯合物; n和m表示相似的整数，范围是1到6; x表示整数或分数，范围为0至10; y表示1到48范围内的整数或分数; z表示整数或分数，范围为0到48; v表示0到24范围内的整数或分数，w表示0到24范围内的整数或分数。另外，本发明描述了通过N的相互作用制备式（I）化合物的方法， N-二甲基哌啶鎓与硼酸和/或含硼的氧化物以及任选地与上述农业可接受的金属氢氧化物或涉及在水和硼酸存在下以及在金属氢氧化物存在下涉及N，N-二甲基哌啶鎓卤化物相互作用的电化学方法通过双极电渗析可用于农业。本发明描述了一种电化学方法，用于制备N，N-二甲基哌啶氢氧化物和具有植物生长调节作用的悬浮浓缩物，该悬浮浓缩物是通过将N，N-二甲基哌啶氢氧化物，选自硼酸和硼酸盐的含硼化合物与增稠剂和水混合而制备的，或将式（I）的化合物与Na 2 B 8 O 13 x 4 H 2 O，增稠剂和水。制备的哌草酸硼酸酯衍生物具有改进的吸湿性和腐蚀活性指数。效果：改进的制备方法，衍生物的有价值的性质。22cl，7 tbl，16 ex
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