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Espumu00e1veis espumados compositions, articles, and pre mixes for the preparation of compositions espumu00e1veis

机译:Espum u00e1veis espumados组合物,物品和预混合物,用于制备espum u00e1veis

摘要

"Espumu00e1veis espumados compositions, articles, and pre mixes for the preparation of compositions espumu00e1veis".Espumu00e1veis compositions which are usable in the manufacture of articles of thermoplastic elastomeric, heat resistant, flexible, espumados, and comprising at least: (a) 100 parts by weight.One or more selectively hydrogenated block copolymer, having at least the blocks the resinous of sandy monovinu00edlico predominantly polymerized, not hydrogenated.And a selectively hydrogenated elastomeric block B, in which the block B before hydrogenation is predominantly a conjugated diene or polymerized dienes.The block copolymer having an apparent molecular weight of at least 250 kg / mol and containing blocks of sandy monovinu00edlico polymerized molecular weight true of at least 18 kg / mol,(b) 5 to 50, preferably from 15 to 40 parts by weight.One or more selectively hydrogenated block copolymers having at least two blocks to 39 resinous of sandy monovinu00edlico predominantly polymerized, not hydrogenated.And a block B 39 elastomeric selectively hydrogenated.In this block B 38 before hydrogenation was derived from a conjugated diene or dienes polymerized as a main component that can be mixed with minor proportions of other glass.Lu00edmeros (e.g., vinyl aromatic), that is, 243 25% by weight, and the block copolymer having an apparent molecular weight in the range of 50000 total 180.000, while the blocks to 39 resinous shows a molecular weight in the range of 3 real 20 kg / mol, preferably 5 to 15 kg / mol, (c) of 25 to 80 parts by weight.A linear crystalline propylene polymer comprising as a main component, having a Vicat softening temperature in the range of 130 398 C 180 198 C and a MFR in the range 0.5 to 30 dg / min and an index of polidispersividade of at least 4.5, (d) of 100 to 250 parts by weight of a softener compatible with blocks B and B 39 , (E) from 0.01 to 3% by weight,With respect to the weight (s) component (s) primary (s) (a) to (E) of a nucleation agent chemical solid in the endothermic group in combination with a blowing agent, and.(f) optionally one or more secondary components selected PPO and / or any resins compatible with the component (a) of the block copolymer, antioxidants, UV stabilisers.Flame retardants, change agents and surface inorganic fillers, and articles espumados derived from such compositions.
机译:“用于制备组合物espum的espum espumados组合物,制品和预混合物”。espumesuvados组合物可用于制造热塑性弹性体,耐热性,柔性,espumados的制品,并且包含至少:(a)100重量份。一种或多种选择性氢化的嵌段共聚物,其嵌段至少主要是聚合沙质单乙烯基树脂的树脂,而不是氢化的;以及一种选择性氢化的弹性体嵌段B,其中嵌段B在氢化主要是共轭二烯或聚合的二烯。该嵌段共聚物的表观分子量至少为250 kg / mol,并且含沙质的单乙烯基二元聚合的嵌段,其真实分子量至少为18 kg / mol,(b) 5至50,优选15至40重量份。一种或多种选择性氢化的嵌段共聚物,其具有至少两个相对于<39>的含沙单乙烯基树脂的嵌段主要是聚合而不是氢化。嵌段B <39>弹性体被选择性氢化。在该嵌段B <38中,氢化前的共轭二烯或二烯是聚合的主要成分,可以与少量其他玻璃混合。 edmeros(例如乙烯基芳族化合物),即<243> 25重量%,表观分子量为50000的嵌段共聚物总计180.000,而<39>树脂质的嵌段则显示分子量(c)25至80重量份的3实际20千克/摩尔,优选5至15千克/摩尔的范围。一种以维卡软化温度为范围的线性结晶丙烯聚合物为主要成分130 <398> C 180 <198> C和0.5至30 dg / min的MFR和至少4.5的树脂分散指数,(d)100至250重量份与嵌段相容的软化剂B和B <39>,(E)为0.01至3重量%,相对于重量吸热基团中成核剂化学固体的主要组分(a)至(E)与发泡剂的组合,以及(f)可选的一种或多种次级组分,选自PPO和/或任何与嵌段共聚物的组分(a)相容的树脂,抗氧化剂,紫外线稳定剂,阻燃剂,改变剂和表面无机填料以及由此类组合物制成的espumados制品。

著录项

  • 公开/公告号BRPI0415116A

    专利类型

  • 公开/公告日2006-11-28

    原文格式PDF

  • 申请/专利权人 KRATON POLYMERS RESEARCH B.V;

    申请/专利号BR2004PI15116

  • 发明设计人 XAVIER MUYLDERMANS;EMANUELLE COIGNOUL;

    申请日2004-09-03

  • 分类号C08J9/00;C08F8/04;C08J9/08;C08L53/02;

  • 国家 BR

  • 入库时间 2022-08-21 20:59:29

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