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Organic electrolyte for lithium sulfur battery and lithium sulfur battery employing the same

机译:用于锂硫电池的有机电解质和使用该有机电解质的锂硫电池

摘要

An organic electrolytic solution containing a lithium salt, an organic solvent, and an oxalate compound, and a lithium battery using the organic electrolytic solution are provided. Due to the oxalate compound, the organic electrolytic solution stabilizes lithium metal and improves the conductivity of lithium ions. Also,, the organic electrolytic solution present invention improves charging/discharging efficiency when used in lithium batteries having a lithium metal anode. Especially when the organic electrolytic solution is used in lithium sulfur batteries, the oxalate compound forms a chelate with lithium ions and improves the ionic conductivity and the charging/discharging efficiency of the battery. In addition, due to the chelation of the lithium ions, negative sulfur ions remain free without interaction with lithium ions, are highly likely to dissolve in an electrolytic solution. As a result, a reversible capacity of sulfur is improved.
机译:提供一种包含锂盐,有机溶剂和草酸盐化合物的有机电解液,以及使用该有机电解液的锂电池。由于使用草酸盐化合物,有机电解液稳定了锂金属并提高了锂离子的电导率。另外,当用于具有锂金属阳极的锂电池中时,本发明的有机电解液提高了充电/放电效率。特别是当有机电解液用于锂硫电池时,草酸盐化合物与锂离子形成螯合物,并改善了离子电导率和电池的充放电效率。另外,由于锂离子的螯合,负硫离子保持自由而不与锂离子相互作用,极有可能溶解在电解液中。结果,提高了硫的可逆容量。

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