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New chiral compounds derived from hexanoic acid esters, process and intermediates for preparation, use in the synthesis of 2- (bromomethyl) 2-ethyl hexanoic chiral.
New chiral compounds derived from hexanoic acid esters, process and intermediates for preparation, use in the synthesis of 2- (bromomethyl) 2-ethyl hexanoic chiral.
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机译:衍生自己酸酯的新手性化合物,其制备方法和中间体,用于合成2-(溴甲基)2-乙基己酸手性。
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5 / Application of the compounds of formula (I) as defined in claim 1 for the preparation of chiral compound of formula (A): (A) wherein a compound of formula (I) is subjected to the action of a reducing agent to obtain a chiral compound of formula (V): (V) wherein R2 has the meaning indicated in claim 1, which is saponified to obtain the chiral acid of formula (VI) (VI) which is subjected to the action of a brominating agent to obtain the chiral compound of formula (a). 6 / application according to claim 5, wherein a compound of formula (I) in which R1 represents R''1 is used, as defined in claim 1. 7 / The compound of formula (III '') wherein B''y R2 are as defined in claim 4. 8 / chiral compounds of formulas: (IV) and (IV1) and (IV ') and (IV''1) in which a , B, C, B '' and R2 are as defined in claim 4. 9 / chiral compounds of formulas: (V) and (VI) in which R2 is as defined in claim 5. 10 / chiral compound of formula (A): (A) 13
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机译:5.如权利要求1所述的式(I)的化合物在制备式(A)的手性化合物中的应用:(A)使式(I)的化合物经受还原剂的作用以获得式(V)的手性化合物:其中R 2具有权利要求1中所述的含义,将其皂化以获得式(VI)的手性酸(VI),其经溴化剂作用而获得式(a)的手性化合物。 6,根据权利要求5的应用,其中使用如权利要求1所定义的其中R 1代表R” 1的式(I)化合物。7 /其中B” y R 2的式(III”化合物)如权利要求4所定义。8 /式(IV)和(IV1)以及(IV′)和(IV″ 1)的手性化合物,其中a,B,C,B″和R2如9.一种式(V)和(VI)的手性化合物,其中R 2如权利要求5所定义。10 /一种式(A)的手性化合物:(A)13
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