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Method for manufacturing an asymmetric arylamine compound, the asymmetric arylamine compound is produced by the production method, and, organic electroluminescent devices using the asymmetric arylamine compounds.
Method for manufacturing an asymmetric arylamine compound, the asymmetric arylamine compound is produced by the production method, and, organic electroluminescent devices using the asymmetric arylamine compounds.
PROBLEM TO BE SOLVED: To provide a method for producing an asymmetric arylamine compound useful for an organic electroluminescent element, or the like, in high purity without using complicate procedures.;SOLUTION: The method for the production of the asymmetric arylamine compound comprises (A) the production of a diarylamino-substituted halogenated aromatic compound by the reaction of a halogenated aromatic compound expressed by the formula (I): (X1)n-Z-(X2)m...(1) (X1 and X2 are halogen atoms different from each other; (n) and (m) are each an integer of 1-4; and Z is an (n+m)-valent aromatic group) with a diarylamine in the presence of a copper catalyst and (B) the reaction of the diarylamino-substituted halogenated aromatic compound produced by the step (A) with a diarylamine different from the diarylamine used in the step A in the presence of a palladium catalyst and a phosphorus-based ligand.;COPYRIGHT: (C)2003,JPO
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