首页> 外国专利> MONOMER CONTAINING ELECTRON-WITHDRAWING GROUP AND ELECTRON-DONATIVE GROUP, AND COPOLYMER AND PROTON-CONDUCTIVE MEMBRANE COMPRISING SAME

MONOMER CONTAINING ELECTRON-WITHDRAWING GROUP AND ELECTRON-DONATIVE GROUP, AND COPOLYMER AND PROTON-CONDUCTIVE MEMBRANE COMPRISING SAME

机译:包含电子吸伸基团和电子给体基团的单体,以及包含相同分子的共聚物和质子导电膜

摘要

A monomer containing an electron-withdrawing group and an electron-donative group which can be easily controlled in the upper limit of the amount of a sulfonic acid, which impairs the mechanical properties of a copolymer, and can provide a sulfonated polymer that forms a proton-conductive membrane having a high proton conductivity over a wide temperature range, an excellent mechanical strength and an excellent proton conductivity and showing inhibited swelling in hot water and an aqueous solution of methanol, and a copolymer obtained from the monomer. A monomer containing an electron-withdrawing group and an electron-donative group represented by the following general formula (1): (see formula I) wherein Y represents a iodine atom, chlorine atom or bromine atom; X represents an electron-withdrawing group; B represents an electron-donative group; and Z represents an aryl group having a specific structure or a monovalent condensed ring hydrocarbon group such as naphthyl group.
机译:含有吸电子基团和电子给体基团的单体,其容易在磺酸量的上限中控制,从而损害共聚物的机械性能,并且可以提供形成质子的磺化聚合物。 -导电膜,其在宽温度范围内具有高的质子传导性,优异的机械强度和质子传导性,并且显示出在热水和甲醇水溶液中的溶胀得到抑制的作用,以及由该单体获得的共聚物。含有下述通式(1)表示的吸电子基和供电子基的单体:(式I)其中,Y表示碘原子,氯原子或溴原子。 X代表吸电子基团; B表示电子给体基团; Z表示具有特定结构的芳基或萘基等一价的稠环烃基。

著录项

  • 公开/公告号CA2377047C

    专利类型

  • 公开/公告日2009-06-30

    原文格式PDF

  • 申请/专利权人 JSR CORPORATION;

    申请/专利号CA20022377047

  • 申请日2002-03-18

  • 分类号C08F232/00;C07C45/71;C07C49/84;C08F216/16;C08G61/12;C08G65/48;C08J5/22;

  • 国家 CA

  • 入库时间 2022-08-21 19:23:35

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