首页> 外国专利> METHOD FOR PRODUCING POLYMERS OF SUSPENSION POLYMERIZATION WITH AVERAGE SIZES OF PARTICLES FROM 1 TO 40 microns, AND ALSO FORMING MASSES AND FORMED PRODUCTS CONTAINING POLYMER OBTAINED BY SUSPENISISISIS

METHOD FOR PRODUCING POLYMERS OF SUSPENSION POLYMERIZATION WITH AVERAGE SIZES OF PARTICLES FROM 1 TO 40 microns, AND ALSO FORMING MASSES AND FORMED PRODUCTS CONTAINING POLYMER OBTAINED BY SUSPENISISISIS

机译:制备平均粒径为1到40微米的悬浮聚合聚合物的方法,还可以形成质量和含SUS的聚合物

摘要

1. A method of producing polymers by suspension polymerization with an average particle size in the range from 1 to 40 μm, in which the polymerizable composition is dispersed and polymerized in the aqueous phase, and the dispersion stabilized by the aluminum compound is obtained at a shear rate of ≥103 s-1, characterized in that they use a polymerizable composition, which accordingly, based on its total weight, contains! a) more than 50.0 wt.%, at least one compound of formula (I),! ! wherein 1R is hydrogen or a linear or branched alkyl group having from 1 to 6 carbon atoms, and residues from 2R to 6R are respectively independently hydrogen or a linear or branched alkyl group having from 1 to 6 carbon atoms, or halogen! b) from 0.1 to 10.0 wt.%, at least one crosslinking agent and! c) less than 49.9% by weight of at least one compound of formula (II),! ! wherein R is hydrogen or methyl, 7R is a linear or branched alkyl group or, optionally, an alkylated cycloalkyl group having from 1 to 40 carbon atoms, and the residues 8R and 9R, respectively, independently of one another, are hydrogen or a group of the formula COOR ′ wherein R 'is hydrogen or an alkyl group having from 1 to 40 carbon atoms. ! 2. The method according to claim 1, characterized in that they use a polymerizable composition, which accordingly, based on its total weight contains! from more than 50.0 to 99.0 wt.%, at least one compound of formula (I),! from 0.1 to 5.0 wt.%, at least one crosslinking agent and! from 0.9 to less than 49.9 wt.%, of at least one compound of the formula (II). ! 3. The method according to claim 2, characterized in
机译:1.一种通过悬浮聚合制备聚合物的方法,其平均粒度为1至40μm,其中所述可聚合组合物在水相中分散和聚合,并且在120℃下获得由铝化合物稳定的分散体。剪切速率≥103s-1,其特征在于它们使用了可聚合的组合物,因此,基于其总重量,其包含! a)大于50.0重量%,至少一种式(I)的化合物,! !其中1R为氢或具有1至6个碳原子的直链或支链烷基,且2R至6R的残基分别独立地为氢或具有1至6个碳原子的直链或支链烷基或卤素! b)0.1至10.0重量%,至少一种交联剂和! c)小于49.9重量%的至少一种式(II)的化合物,! !其中R是氢或甲基,7R是直链或支链烷基,或任选地,具有1至40个碳原子的烷基化的环烷基,且残基8R和9R分别彼此独立地是氢或一个基团式COOR'的通式,其中R'是氢或具有1至40个碳原子的烷基。 ! 2.根据权利要求1所述的方法,其特征在于,它们使用可聚合的组合物,因此基于其总重量包含!大于50.0至99.0重量%,至少一种式(I)化合物! 0.1至5.0重量%,至少一种交联剂和! 0.9至小于49.9重量%的至少一种式(II)化合物。 ! 3.根据权利要求2所述的方法,其特征在于,

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