首页> 外国专利> NICKEL COBALT COMPOUND HYDROXIDE AND METHOD FOR PRODUCING THE SAME, AND POSITIVE ELECTRODE ACTIVE MATERIAL FOR NONAQUEOUS ELECTROLYTE SECONDARY BATTERY OBTAINED BY USING THE COMPOUND HYDROXIDE

NICKEL COBALT COMPOUND HYDROXIDE AND METHOD FOR PRODUCING THE SAME, AND POSITIVE ELECTRODE ACTIVE MATERIAL FOR NONAQUEOUS ELECTROLYTE SECONDARY BATTERY OBTAINED BY USING THE COMPOUND HYDROXIDE

机译:镍钴复合氢氧化物及其制备方法以及使用该复合氢氧化物获得的用于非电解质二次电池的正极活性物质

摘要

PROBLEM TO BE SOLVED: To provide a nickel cobalt compound hydroxide which has a large particle diameter, has high density, and is nearly spherical, and which is suitable as a precursor of a positive electrode active material for a nonaqueous electrolyte secondary battery to further heighten energy density of a battery by improving packing density.SOLUTION: In a method for producing a nickel cobalt compound hydroxide, when the nickel cobalt compound hydroxide is obtained by: supplying a mixed aqueous solution (a) including a nickel salt and a cobalt salt and an aqueous solution (b) including an ammonium ion supplying body; simultaneously making a reaction take place by supplying a caustic alkali aqueous solution (c) while stirring the reaction solution; subjecting the crystallized nickel cobalt compound hydroxide particles to solid-liquid separation; washing it by water; and drying it, the reaction solution is stirred by using a stirring blade having an inclination of 45° or less to the horizontal plane, wherein a rate of an amount supplied of the mixed aqueous solution (a) versus an amount of the reaction solution per supply port is made to be 0.04 vol.%/min or less.
机译:解决的问题:提供粒径大,密度高且接近球形的镍钴复合氢氧化物,其适于进一步用作非水电解质二次电池用正极活性物质的前体。解决方案:在制备镍钴复合氢氧化物的方法中,当通过以下方式获得镍钴复合氢氧化物时:提供包含镍盐和钴盐的混合水溶液(a),并(b)包括铵离子供给体的水溶液;通过在搅拌反应溶液的同时提供苛性碱水溶液(c)来同时进行反应。使结晶的镍钴复合氢氧化物颗粒固液分离;用水冲洗;干燥后,使用相对于水平面倾斜45°以下的搅拌叶片搅拌反应溶液,其中,混合水溶液(a)的供给量相对于每供给口为0.04vol。%/ min以下。

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