β- hydroxy hydroperoxides, the manufacturing method of ketones and carboxylic acids and their catalytic

摘要

PROBLEM TO BE SOLVED: To provide a method for producing a β-hydroxyhydroperoxide, a ketone and a carboxylic acid by oxidizing a trisubstituted olefin with hydrogen peroxide.;SOLUTION: This method for producing a β-hydroxyhydroperoxide, a ketone and a carboxylic acid is characterized by comprising reaction of a trisubstituted olefin with hydrogen peroxide in the presence of a metal oxide catalyst prepared by reaction between hydrogen peroxide and at least one metal compound selected from the group consisting of metallic tungsten, metallic molybdenum, a tungsten compound made from tungsten and a group IIIb, group IVb, group Vb or group VIb element except oxygen, and a molybdenum compound made from molybdenum and a group IIIb, group IVb, group Vb or group VIb element except oxygen.;COPYRIGHT: (C)2002,JPO