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The formation of metal particles on a solid support has a base of the oxide and provided with two distinct chemical functions grafted

机译:在固体载体上形成的金属颗粒具有氧化物的碱,并具有接枝的两种不同的化学功能

摘要

The metallic particles are formed on a solid support based on oxide, for example, of silica, by in situ reduction of metal ions and the fastening of the said metallic particles on the support in a single step. This step consists in contacting the metal ions with the support, that - latter having previously been functionalized in a manner appropriate. More particularly, the support is functionalized by covalent bonds by two specific and different types of chemical functions. The first function used is a chemical function chelating to the metal ions and / or to the corresponding metal to metal ions, while the second function is a function of reducing chemical for metal ions. By way of example, the first function may be a thiol and the second function may be the ethylene diamine.
机译:通过在单个步骤中原位还原金属离子并将所述金属颗粒固定在载体上,将金属颗粒形成在基于例如二氧化硅的氧化物的固体载体上。该步骤在于使金属离子与载体接触,该载体先前已经以合适的方式被官能化。更特别地,通过两种特定且不同类型的化学功能通过共价键使载体官能化。所使用的第一功能是螯合金属离子和/或相应的金属与金属离子的化学功能,而第二功能是还原金属离子的化学功能。举例来说,第一官能团可以是硫醇,第二官能团可以是乙二胺。

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