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Hydrogen storage alloy, hydrogen storage alloy electrode using the hydrogen storage alloy, and nickel-hydrogen secondary battery
Hydrogen storage alloy, hydrogen storage alloy electrode using the hydrogen storage alloy, and nickel-hydrogen secondary battery
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机译:储氢合金,使用该储氢合金的储氢合金电极和镍氢二次电池
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摘要
PPROBLEM TO BE SOLVED: To provide a rare earth-Mg-Ni hydrogen storing alloy having high hydrogen equilibrium pressure while keeping alkali resistance and hydrogen storing amount; and a hydrogen storing alloy electrode using the hydrogen storing alloy; and a nickel hydrogen secondary battery having high capacity, long cycle life, and high working voltage. PSOLUTION: The nickel hydrogen secondary battery contains hydrogen storing alloy particles 36 in a negative electrode 26, and the hydrogen storing alloy has a composition represented by general formula: (NdSBa/SBDySBb/SBASBc/SB)SB1-w/SBMgSBw/SBNiSBx/SBAlSBy/SBTSBz/SB. In the formula, A and T each represent at least one element selected from the group comprising La, Pr and the like, and the group comprising V, Nb and the like; subscripts a, b, and c each satisfy the relation represented by a0, b0, c0, a+b+c=1; subscripts w, x, and z each are in the range represented by 0w1, 0.05y0.35, 0z0.5, and 3.2x+y+z3.8. PCOPYRIGHT: (C)2009,JPO&INPIT
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解决方案:镍氢二次电池在负极26中包含储氢合金颗粒36,并且该储氢合金具有由以下通式表示的组成:(Nd a SB> Dy b SB> A c SB>) 1-w SB> Mg w SB> Ni x SB> Al y SB > T z SB>。式中,A和T分别表示选自La,Pr等,V,Nb等的组中的至少一种元素。下标a,b和c分别满足由a> 0,b> 0,c> 0,a + b + c = 1表示的关系。下标w,x和z分别在0 版权:(C)2009,日本特许厅&INPIT