Amide acid n - (tetrazol - 5 - il - arilcarboxilico) and N - (5 - (IL) - arilcarboxilico and their use as herbicides

摘要

Describes acid amides of N - (5 - tetrazol - il - arilcarboxu00edlico) and N - (5 - (IL) arilcarboxu00edlico as Selective herbicides, useful in the fight against Weeds.Claim 1: N - (tetrazol acid amides arilcarboxu00edlico IL - 5 - and N - (-) - 5 - (IL) arilcarboxu00edlico of formula (1) or its Salts, which means N or CY; b means N or CH, X is Halogen, Nitro, cyano, Formilo, Sulfocianuro C1 - 6 alkyl, alkyl, Halo alquenilo C1 - C2 - 6 6 Halo - alquenilo alquinilo C2 C2 - 6, 6 -, Halo - alquinilo cycloalkyl C3 C3 - 6, 6 -, Halo - cycloalkyl C3 - 6Cicloalquil C1 - C3 - 6 - 6 alkyl, Halo cicloalquil C1 - C3 alkyl - 6 - 6, COR1, coor1, ocoor1, nr1coor1, C (o) n (2 nr1c (R1), or 2) n (R1), OC (o) n (R1) 2, C (o) nr1or1, OR1, ocor1, u00d3so2r2, S (o) NR2, so2or1, so2n (R1) 2, nr1so2r2, nr1cor1, alkyl C1 - 6 - S (o) NR2, alkyl alkyl OR1 - C1 - 6, 6 - ocor1 C1, C1 alkyl - 6 - oso2r2, alkyd Il - 6 - co2r1 C1, C1 - 6 - so2or1 alkyl, alkyl C1 - 6 - 2 (R1, C1 alkyl) - 6 - (2 so2n R1, C1 alkyl) - 6 - nr1cor1,Alkyl C1 - 6 - nr1so2r2, nr1r2, P (o) (OR5 ch2p (2), or (2) OR5), C1 - 6 - heteroaryl alkyl, alkyl C1 - 6 - heterociclilo, being replaced the last two mentioned remains in every case with s remains Halogen, alkyl haloalquilo C1 C1 - 6 - 6 S (o) n - alkyl alkoxy C1 C1 - 6, 6 - alkoxy -, Halo - 6 and C1, and containing L heterociclilo n oxo groups and means; Hydrogen, halogen, Nitro, cyano, Sulfocianuro,C1 - 6 alkyl alkyl, Halo - C1 - C2 - alquenilo 6, 6, 6 alquenilo C2 - Halo - Halo, alquinilo C2 - 6, 6 - alquinilo C2 - C3, C3 cicloalquenilo cycloalkyl - 6, - 6, - 6 cicloalquil halocicloalquilo C3, C3 C1 - 6 6 - alkyl -, Halo - cicloalquil alkyl C1 - C3 - 6 - 6, COR1, coor1, ocoor1, nr1coor1, C (o) n (R1) 2, nr1c (o) n (2, OC (R1) (o) n (R1) 2, CO (nor1) R1, nr1so2r2, nr1cor1, OR1, oso2r2, S (o) NR2, so2or1, so2n (R1) 2Alkyl C1 - 6 - S (o) NR2, alkyl alkyl OR1 - C1 - 6, 6 - ocor1 C1, C1 - 6 - oso2r2 alkyl, alkyl alkyl - 6 - co2r1 C1, C1 - 6 - CN, - 6 - so2or1 C1 alkyl, alkyl C1 - 6 - 2 (R1) C1 alkyl so2n (R1) - 6 - 2, 6 - nr1cor1 C1 alkyl, alkyl C1 - 6 - nr1so2r2 (R1), n 2, P (o) (OR5 ch2p (2), or (2) OR5), alkyl phenyl alkyl - C1 - 6, 6 - C1 - heteroaryl, C1 - 6 - heterociclilo alkyl, phenyl or heteroaryl heterociclilo,Being replaced the last 6 remains in every case with Remnants of the group formed by alkyl Halogen, Nitro, cyano, C1 - 6, 6 - Halo - C1 C3 alkyl, cycloalkyl - 6 S (o) n - alkyl alkoxy C1 C1 - 6, 6 - alkoxy -, Halo - alkoxy C1 C1 6 - 6 and cianometilo c1-4 alkyl, and containing N or heterociclilo groups XO; Z means Sulfocianuro Ciano, halogen, alkyl, Halo alquenilo C2 C1 - 6, 6 -, Halo - alquenilo C2 - 6Alquinilo 6 C2 -, Halo - alquinilo C2 C3 - 6 - 6, cycloalkyl, Halo cicloalquil cycloalkyl C3 - 6, 6 - C1 - C3 - 6 alkyl, Halo cicloalquil C3 alkyl C1 - 6 - 6, COR1, coor1, ocoor1, nr1coor1, C (o) n (R1) 2 nr1c (o) N (R1) 2, OC (o) n (R1) 2, C (OR) nr1or1, oso2r2, S (o) NR2, so2or1, so2n (R) 2, nr1so2r2 nr1cor1, C1 -, alkyl - or s (6 C1 - NR2), alkyl alkyl OR1 - 6, 6 - ocor1 C1, C1 - 6 - oso2r2 alkyl, alkyl alkyl - 6 - co2r1 C1, C1 - 6 - so2or1,Alkyl C1 - 6 - (2 - alkyl R1), C1 (R1) so2n 6 - 2, 6 - nr1cor1 C1 alkyl, alkyl C1 - 6 - nr1so2r2 (R1), n 2, P (o) (2 OR5), phenyl or heteroaryl, heterociclilo, being replaced in the past three remains each case with Remnants of the group formed by alkyl Halogen, Nitro, cyano, C1 - 6 - 6 - C1 alkyl, Halo, Ci Cloalquilo C3 - 6 S (o) n - alkyl alkoxy C1 C1 - 6, 6 - alkoxy - or Halo C1 - 6The heterociclilo and containing N or oxo groups, Z may also mean Hydrogen, alkyl or alkoxy C1 C1 - 6 - 6, in case they represent and the Rest (R or S) NR2, means ch2r6, CH2 - groups with heterociclilo substituted cycloalkyl C3 oxo m, T - 7 substituted with alkyl groups C1 - 6 Rent - 6, C2, Ci 7 cloalquilo C3 alkyl, Halo alquenilo C2 C2 - 6, 6 -, Halo - alquenilo C2 - 6Alquinilo C2 or C2 - 6 - 6 - alquinilo Halo substituted or replaced in each case with Remnants of the group formed by nitro, cyano, Hydroxy, Oxo, sir53, PO (2 OR5), S (o) n - alkyl alkoxy C1 C1 - 6, 6 - alkoxy -, Halo - C1 (6, N R3) 2, cor3, ocor3, nr3cor3, nr3so2r4 cycloalkyl, c3-6, heterociclilo phenyl heteroaryl,,, Q - heteroaryl, heterociclilo Q - Q - Q -, phenyl and benzyl,The remains being substituted cycloalkyl c3-6, heteroaryl, heterociclilo, phenyl heteroaryl heterociclilo Q -, Q - Q - Q -, phenyl and benzyl substituents in each case s of the Group comprising Ethyl, Methyl, methoxy, Nitro, cyano, trifluoromethyl and Halogen, and containing the heterociclilo and CIC Loalquilo n Means or oxo groups; Q, s or NR1; r1 is Hydrogen, alkyl C1 - 6Haloalquilo C1 - C2 - alquenilo 6, 6, 6 alquinilo haloalquenilo C2, C2 - 6 - 6, haloalquinilo C2, C3 C3 cicloalquenilo cycloalkyl - 6, - 6, - 6 halocicloalquilo C1 - C3 alkyl, o-alkyl C1 - 6 - 6, 6 - cicloalquil C1 C3 alkyl, phenyl - 6 phenyl alkyl C1 - 6, 6 - C1 - heteroaryl heteroaryl alkyl, alkyl, heterocycle, C 1 - 6 - heterociclilo C1 -, alkyl - or heteroaryl alkyl - 6, 6 - or - C1 - heterociclilo,Alkyl C1 - 6 - NR1 - heteroaryl alkyl C1 - 6, - NR1 - heterociclilo, being replaced the last 21 remains above s formed by Remnants of the cyano Group, halogen, Nitro, Sulfocianuro, OR3, S (OR) NR4 (R3), n 2, nr3or3, cor3, ocor3, scor4, nr3cor3, nr3so2r4, co2r3, cosr4, (R3) 2 and c1-4 alkoxy - ALCO Xicarbonilo C2 - 6, and the N groups heterociclilo containing oxo alkyl; R2 means C1 - 6Haloalquilo C1 - C2 - alquenilo 6, 6, 6 alquinilo haloalquenilo C2, C2 - 6 - 6, haloalquinilo C2, C3 C3 cicloalquenilo cycloalkyl - 6, - 6, - 6 halocicloalquilo C1 - C3 alkyl, o-alkyl C1 - 6 - 6, 6 - cicloalquil C2 C3 alkyl, phenyl - 6 phenyl alkyl C1 - 6, 6 - C1 - heteroaryl heteroaryl alkyl, alkyl, heterociclilo, C1 - 6 - heterociclilo C1 -, alkyl - or heteroaryl alkyl - 6, 6 - or - C1 - heterociclilo,Alkyl C1 - 6 - NR1 - heteroaryl alkyl C1 - 6, - NR1 - heterociclilo, being replaced the last 21 remains above s formed by Remnants of the cyano Group, halogen, Nitro, Sulfocianuro, OR3, S (OR) NR4 (R3), n 2, nr3or3, cor3, ocor3, scor4, nr3cor3, nr3so2r4, co2r3, cosr4, (R3) 2 and c1-4 alkoxy - ALCO Xicarbonilo C2 - 6, and the N heterociclilo containing oxo groups; R3 is Hydrogen, alkyl C1 - 6Alquenilo C2 - 6 - 6, alquinilo C2 or C3, C3 cicloalquil cycloalkyl - 6 - 6 - 6 - C1 alkyl alkyl; R4 means C1 C2 - 6 - 6, alquenilo alquinilo C2 or C3 - 6 - 6, cycloalkyl or cicloalquil C1 C3 alkyl - 6 - 6; R5 is c1-4 alkyl; R6 means ocoor4, nr4coor4, S (o) n - alkyl of C1 - 6 S (o) n - haloalquilo C1 - 6, Nit Ro, cyano, sir53, PO (2 OR5), heterociclilo or cycloalkyl,The last two TRACES containing oxo Hydroxy groups or groups mentioned m; M is 1 or 2; n is 0, 1 or 2; S = 0, 1, 2 or 3; T means 1, 2, 3, or 4 or means; 1, 2, 3, 4 or 5.