Manufacturing method of metal/silica catalyst support via branched metal silicate structures and metal/silica catalyst support thereof

摘要

PURPOSE: A metal and silica doped catalyst and a manufacturing method thereof are provided to uniformly dip metal particles with 20 wt% or higher concentration by developing pores and be thermally stable by not causing sintering between the metal particles at 700C of high temperature heat treatment. CONSTITUTION: A manufacturing method of a metal and a silica doped catalyst comprises the following steps: manufacturing metal, metal oxide, or an alloy nano particles by decomposing organometallic compounds at high temperature by mixing with organic surfactant and organic solvent; coating the nano-particles with silica using micro emulsion; converting the metal and silica core-shell structure into the branched metal silicate structure using a high temperature hydrothermal reaction; and obtaining metal doped catalyst which is high deposited in silica by reducing and annealing the metal silicate structure under a high temperature hydrogen condition. The metal or metal oxide nano-particle and alloy nano-particle are manufactured in a non-aqueous system. [Reference numerals] (AA) Metal salt + organic surfactant; (BB) Thermal reduction or decomposition; (CC) Metal or metal oxide nanoparticles; (DD) Silica coating using microemulsion; (EE) Metal or metal oxide/silica core-shell nanoparticles; (FF) Hydrothermal reaction; (GG) Branch type metal silicate structure; (HH) High temperature plasticizing or reduction; (II) Metal/silica doped catalyst