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Michael acceptor with a large number of hydroxyl groups, and Michael addition products derived therefrom

机译:具有大量羟基的迈克尔受体和由其衍生的迈克尔加成产物

摘要

Provided is a Michael addition product prepared from a multifunctional acryl monomer having multiple hydroxyl groups allowing introduction of acryl functional groups, as a Michael acceptor, and a Michael donor. The Michael addition product is a novel multifunctional compound having an oligomer and a photoinitiator moiety in the molecule. Since it can be cured under a standard UV curing condition without having to add a photoinitiator, it is reduced to air pollution or health problem. Therefore the superior physical properties were obtained by cured coatings without surface tackiness. In addition, its hydroxyl groups allow, through isocyanate bonding or introduction of acryl groups, 3-dimensional crosslinking and molecular and compositional design for improving expandability, friction, and reactivity and hydrophilicity for self-adhesion, hardness of cured film, or the like. Consequently, a very useful, multifunctional or water-dispersible coating composition may be prepared.
机译:本发明提供一种迈克尔加成产物,其由具有多个允许引入丙烯酸官能团的羟基的多官能丙烯酸单体作为迈克尔受体和迈克尔供体而制备。迈克尔加成产物是在分子中具有低聚物和光引发剂部分的新型多功能化合物。由于可以在标准的UV固化条件下进行固化而无需添加光引发剂,因此可以减少空气污染或健康问题。因此,通过固化的涂层而没有表面粘性可获得优异的物理性能。另外,其羟基通过异氰酸酯键或丙烯酸基团的引入允许3维交联以及分子和组成设计,以改善膨胀性,摩擦性,以及对于自粘性,固化膜的硬度等的反应性和亲水性。因此,可以制备非常有用的,多功能的或水分散性的涂料组合物。

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