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SUPRAMOLECULAR COMPLEXES AS PHOTOCATALYSTS FOR REDUCTION
SUPRAMOLECULAR COMPLEXES AS PHOTOCATALYSTS FOR REDUCTION
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机译:超分子复合物作为光催化还原剂
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摘要
Supramolecular complexes, methods and systems for photocatalysis of the reduction of substrates are described. The supramolecular complexes of the invention have a light absorbing metal center, an electron collector ligand and a catalytically active metal. When the supramolecular complexes are exposed to radiant energy, the light absorbing metal center creates a charge that is transferred to the electron collector ligand to form a charge transfer state. The charge is then transferred through the catalytically active metal to a substrate, cause the reduction of the substrate, e.g. the reduction of water to molecular hydrogen.
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