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Urea production process and plant and method for modernizing a urea production plant

机译:尿素生产工艺和设备以及尿素生产设备现代化的方法

摘要

The invention relates to processes and plants for producing urea from ammonia and carbon dioxide and can be used in the chemical industry and in the production of fertilizers. The process of producing urea by synthesizing same from carbon dioxide and ammonia at high temperatures and pressures with the two stage distillation of the synthesis products (at 1.5-2.5 and 0.2-0.5 MPa) and the recirculation of unreacted ammonia and carbon dioxide in the form of an aqueous solution of carbon ammounium salts (CAS) additionally includes a stage for the adiabatic separation of the synthesis products at a pressure of 8-12 MPa followed by distillation at the same pressure in a stream of carbon dioxide representing 40 60% of the total amount thereof introduced into the process; the corresponding plant is additionally provided with the equipment necessary to carry out this stage. The gases isolated during this distillation stage together with a portion of the adiabatic separation gases are subjected to absorption condensation at the same pressure of 8-12 MPa and are returned in the form of a CAS solution for synthesis. The technical result achieved by using the proposed process and plant and by the modernization of a plant for the implementation of the proposed process is an increase in the degree of conversion of the initial reagents in the synthesis zone.
机译:本发明涉及由氨和二氧化碳生产尿素的方法和设备,可用于化学工业和化肥的生产。通过在高温高压下从二氧化碳和氨中合成尿素并通过两步蒸馏合成产物(在1.5-2.5和0.2-0.5 MPa下)和未反应的氨和二氧化碳形式的再循环来生产尿素的过程碳铵盐(CAS)的水溶液还包括一个用于在8-12 MPa压力下绝热分离合成产物的步骤,然后在相同压力下在占40%的二氧化碳流中进行蒸馏。引入过程的总量;另外,还为相应的工厂提供了执行此阶段所需的设备。在该蒸馏阶段中分离出的气体与一部分绝热分离气体一起在8-12 MPa的相同压力下进行吸收缩合,并以CAS溶液的形式返回以进行合成。通过使用所提出的方法和设备以及通过对工厂进行现代化以实施所提出的方法而获得的技术结果是合成区中初始试剂转化率的提高。

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