首页> 外国专利> PROCESS FOR THE PREPARATION OF PARTICLES SUITABLE FOR CATALYZING OXYGEN REDUCTION OR CONDUCTIVE HYDROGEN OXIDATION OF PROTONS BY GRAFTING SURFACE OF PROTON-CONDUCTING POLYMERS

PROCESS FOR THE PREPARATION OF PARTICLES SUITABLE FOR CATALYZING OXYGEN REDUCTION OR CONDUCTIVE HYDROGEN OXIDATION OF PROTONS BY GRAFTING SURFACE OF PROTON-CONDUCTING POLYMERS

机译:通过接枝质子传导性聚合物表面制备适合催化质子的氧还原或质子氢氧化的颗粒的方法

摘要

The invention relates to a method for preparing particles comprising a material capable of catalyzing the reduction of oxygen or the oxidation of hydrogen, said particles being functionalized by polymers comprising at least one repeating unit bearing at least one proton-conducting group, and said particles being covalently bonded to a carbon material, said method comprising: a step a) of contacting particles, comprising a material capable of catalyzing the reduction of oxygen or the oxidation of hydrogen, with a polymer comprising at least one repeating unit bearing at least one proton-conducting group and comprising at least one portion corresponding to an organic radical of a compound that is an initiator for ATRP polymerization, said radical comprising at least one group capable of being grafted onto the surface of said particles, whereby particles, onto which polymers comprising at least one repeating unit bearing at least one proton-conducting group are grafted, are obtained.
机译:本发明涉及一种制备颗粒的方法,该颗粒包含能够催化氧的还原或氢的氧化的材料,所述颗粒被包含至少一个带有至少一个质子传导基团的重复单元的聚合物官能化,并且所述颗粒为共价键合到碳材料上的方法,所述方法包括:步骤a)使包含能催化氧的还原或氢的氧化的材料的颗粒与包含至少一个带有至少一个质子的重复单元的聚合物接触。导电基团,其包含至少一部分对应于作为ATRP聚合引发剂的化合物的有机基团,所述基团包含至少一个能够接枝到所述颗粒表面的基团,从而在其上包含聚合物的聚合物获得至少一个带有至少一个质子传导基团的重复单元。

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